S. V. Baryshnikova, M. V. Arsen’ev, N. O. Druzhkov, G. K. Fukin, E. V. Baranov, A. V. Piskunov
{"title":"基于立体受阻邻苯二酚配体的氧化还原活性锡(IV)配合物","authors":"S. V. Baryshnikova, M. V. Arsen’ev, N. O. Druzhkov, G. K. Fukin, E. V. Baranov, A. V. Piskunov","doi":"10.1134/S1070328423600778","DOIUrl":null,"url":null,"abstract":"<p>The oxidative addition of sterically hindered 3,6-dicyclohexyl-<i>o</i>-benzoquinone (L<sup>1</sup>), 3,5-di<i>-tert-</i>octyl<i>-o-</i>benzoquinone (L<sup>2</sup>), 4-<i>tert-</i>octyl<i>-o-</i>benzoquinone (L<sup>3</sup>), and 3,5-bis(2-phenylpropyl)-<i>o-</i>benzoquinone (L<sup>4</sup>) to tin(II) chloride in THF affords the corresponding tin(IV) catecholate complexes with the general formula RCatSnCl<sub>2</sub>·2THF, where Cat is the catecholate fragment; and R is 3,6-<i>с</i>-Hex (<b>I</b>), 3,5-<i>tert</i>-Oct (<b>II</b>), 4-<i>tert</i>-Oct (<b>III</b>), and 3,5-C(Me)<sub>2</sub>Ph (<b>IV</b>), regardless of the molar ratio of the starting reactants. The molecular structures of substituted <i>o-</i>benzoquinone L<sup>4</sup> and complexes <b>I</b> and <b>III</b> in the crystalline form are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2259370 (L<sup>4</sup>), 2259371 (<b>I</b>), and 2259372 (<b>III</b>)). The oxidation–reduction properties of synthesized compounds <b>I</b>–<b>IV</b> are studied by cyclic voltammetry.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 1","pages":"49 - 60"},"PeriodicalIF":1.1000,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Redox-Active Tin(IV) Complexes Based on Sterically Hindered Catecholate Ligands\",\"authors\":\"S. V. Baryshnikova, M. V. Arsen’ev, N. O. Druzhkov, G. K. Fukin, E. V. Baranov, A. V. Piskunov\",\"doi\":\"10.1134/S1070328423600778\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The oxidative addition of sterically hindered 3,6-dicyclohexyl-<i>o</i>-benzoquinone (L<sup>1</sup>), 3,5-di<i>-tert-</i>octyl<i>-o-</i>benzoquinone (L<sup>2</sup>), 4-<i>tert-</i>octyl<i>-o-</i>benzoquinone (L<sup>3</sup>), and 3,5-bis(2-phenylpropyl)-<i>o-</i>benzoquinone (L<sup>4</sup>) to tin(II) chloride in THF affords the corresponding tin(IV) catecholate complexes with the general formula RCatSnCl<sub>2</sub>·2THF, where Cat is the catecholate fragment; and R is 3,6-<i>с</i>-Hex (<b>I</b>), 3,5-<i>tert</i>-Oct (<b>II</b>), 4-<i>tert</i>-Oct (<b>III</b>), and 3,5-C(Me)<sub>2</sub>Ph (<b>IV</b>), regardless of the molar ratio of the starting reactants. The molecular structures of substituted <i>o-</i>benzoquinone L<sup>4</sup> and complexes <b>I</b> and <b>III</b> in the crystalline form are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2259370 (L<sup>4</sup>), 2259371 (<b>I</b>), and 2259372 (<b>III</b>)). The oxidation–reduction properties of synthesized compounds <b>I</b>–<b>IV</b> are studied by cyclic voltammetry.</p>\",\"PeriodicalId\":759,\"journal\":{\"name\":\"Russian Journal of Coordination Chemistry\",\"volume\":\"50 1\",\"pages\":\"49 - 60\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-05-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Coordination Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070328423600778\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328423600778","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
摘要
摘要将立体受阻的 3,6-二环己基邻苯醌(L1)、3,5-二叔辛基邻苯醌(L2)、4-叔辛基邻苯醌(L3)和 3、在四氢呋喃中将 5-双(2-苯基丙基)-邻苯醌(L4)与氯化锡(II)反应,可得到相应的邻苯二酚锡(IV)配合物,通式为 RCatSnCl2-2THF,其中 Cat 为邻苯二酚片段;和 R 是 3,6-с-Hex (I)、3,5-叔-Oct (II)、4-叔-Oct (III) 和 3,5-C(Me)2Ph (IV),与起始反应物的摩尔比无关。通过 X 射线衍射 (XRD)(CIF 文件 CCDC 编号:2259370 (L4)、2259371 (I) 和 2259372 (III))确定了晶体状取代邻苯醌 L4 和配合物 I 和 III 的分子结构。通过循环伏安法研究了合成化合物 I-IV 的氧化还原特性。
Redox-Active Tin(IV) Complexes Based on Sterically Hindered Catecholate Ligands
The oxidative addition of sterically hindered 3,6-dicyclohexyl-o-benzoquinone (L1), 3,5-di-tert-octyl-o-benzoquinone (L2), 4-tert-octyl-o-benzoquinone (L3), and 3,5-bis(2-phenylpropyl)-o-benzoquinone (L4) to tin(II) chloride in THF affords the corresponding tin(IV) catecholate complexes with the general formula RCatSnCl2·2THF, where Cat is the catecholate fragment; and R is 3,6-с-Hex (I), 3,5-tert-Oct (II), 4-tert-Oct (III), and 3,5-C(Me)2Ph (IV), regardless of the molar ratio of the starting reactants. The molecular structures of substituted o-benzoquinone L4 and complexes I and III in the crystalline form are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2259370 (L4), 2259371 (I), and 2259372 (III)). The oxidation–reduction properties of synthesized compounds I–IV are studied by cyclic voltammetry.
期刊介绍:
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.