{"title":"活性蔗渣灰在高早期强度土工聚合物中的有效功能","authors":"Pakamon Kittisayarm, Chayanee Tippayasam, Cristina Leonelli, Chanchana Thanachayanont, Anucha Wannagon, Greg Heness, Duangrudee Chaysuwan","doi":"10.1007/s41779-024-01008-8","DOIUrl":null,"url":null,"abstract":"<div><p>High early-strength concrete and geopolymer offer advantages of faster construction and require less curing time than traditional concrete. Bagasse ash (BA), an inert pozzolan with low reactivity in alkaline media, was activated with 10M NaOH to enhance its porosity and surface area. It was then incorporated into an 80:20 wt% mixture of metakaolin (MK) and BA to improve the early-strength properties of geopolymers. This study investigates the effects of varying amounts of activated bagasse ash (ABA) on the physical and mechanical properties of a binary MK-BA-based geopolymer. The pozzolan-to-alkali ratio was maintained at 1:1, with a difference of 10M NaOH-to-Na<sub>2</sub>SiO<sub>3</sub>. The results indicated that the compressive strength of formulation with 50 wt% ABA increased by approximately 33% compared with formulation without ABA. XRD analysis showed a sodium aluminum silicate peak at 3 days, which decreased after 28 days, confirmed by SEM/EDS. The transformation of sodium aluminosilicate gel into a dense geopolymer matrix was observed, with IR spectra demonstrating the presence of Si–O-(Si/Al) bonds contributing to high compressive strength formulations. Overall, the ABA led to the early formation of the geopolymer 3D network with high compressive strength values.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 4","pages":"1071 - 1083"},"PeriodicalIF":1.8000,"publicationDate":"2024-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effective function of activated bagasse ash for high early strength geopolymer\",\"authors\":\"Pakamon Kittisayarm, Chayanee Tippayasam, Cristina Leonelli, Chanchana Thanachayanont, Anucha Wannagon, Greg Heness, Duangrudee Chaysuwan\",\"doi\":\"10.1007/s41779-024-01008-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>High early-strength concrete and geopolymer offer advantages of faster construction and require less curing time than traditional concrete. Bagasse ash (BA), an inert pozzolan with low reactivity in alkaline media, was activated with 10M NaOH to enhance its porosity and surface area. It was then incorporated into an 80:20 wt% mixture of metakaolin (MK) and BA to improve the early-strength properties of geopolymers. This study investigates the effects of varying amounts of activated bagasse ash (ABA) on the physical and mechanical properties of a binary MK-BA-based geopolymer. The pozzolan-to-alkali ratio was maintained at 1:1, with a difference of 10M NaOH-to-Na<sub>2</sub>SiO<sub>3</sub>. The results indicated that the compressive strength of formulation with 50 wt% ABA increased by approximately 33% compared with formulation without ABA. XRD analysis showed a sodium aluminum silicate peak at 3 days, which decreased after 28 days, confirmed by SEM/EDS. The transformation of sodium aluminosilicate gel into a dense geopolymer matrix was observed, with IR spectra demonstrating the presence of Si–O-(Si/Al) bonds contributing to high compressive strength formulations. Overall, the ABA led to the early formation of the geopolymer 3D network with high compressive strength values.</p></div>\",\"PeriodicalId\":673,\"journal\":{\"name\":\"Journal of the Australian Ceramic Society\",\"volume\":\"60 4\",\"pages\":\"1071 - 1083\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-05-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Australian Ceramic Society\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s41779-024-01008-8\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Australian Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s41779-024-01008-8","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
摘要
与传统混凝土相比,高早强混凝土和土工聚合物具有施工速度快、养护时间短等优点。蔗渣灰(BA)是一种在碱性介质中反应活性较低的惰性胶结料,用 10M NaOH 对其进行活化,以提高其孔隙率和表面积。然后将其掺入偏高岭土(MK)和 BA 80:20 wt% 的混合物中,以改善土工聚合物的早期强度性能。本研究调查了不同数量的活性蔗渣灰(ABA)对基于 MK-BA 的二元土工聚合物的物理和机械性能的影响。混合料与碱的比例保持为 1:1,10M NaOH 与 Na2SiO3 之比为 1:1。结果表明,与不含 ABA 的配方相比,含 50 wt% ABA 的配方的抗压强度提高了约 33%。XRD 分析表明,在 3 天时出现了铝硅酸钠峰,28 天后峰值减小,SEM/EDS 证实了这一点。观察到铝硅酸钠凝胶转变为致密的土工聚合物基质,红外光谱显示,Si-O-(Si/Al)键的存在有助于提高配方的抗压强度。总之,ABA 使土工聚合物三维网络尽早形成,并具有较高的抗压强度值。
Effective function of activated bagasse ash for high early strength geopolymer
High early-strength concrete and geopolymer offer advantages of faster construction and require less curing time than traditional concrete. Bagasse ash (BA), an inert pozzolan with low reactivity in alkaline media, was activated with 10M NaOH to enhance its porosity and surface area. It was then incorporated into an 80:20 wt% mixture of metakaolin (MK) and BA to improve the early-strength properties of geopolymers. This study investigates the effects of varying amounts of activated bagasse ash (ABA) on the physical and mechanical properties of a binary MK-BA-based geopolymer. The pozzolan-to-alkali ratio was maintained at 1:1, with a difference of 10M NaOH-to-Na2SiO3. The results indicated that the compressive strength of formulation with 50 wt% ABA increased by approximately 33% compared with formulation without ABA. XRD analysis showed a sodium aluminum silicate peak at 3 days, which decreased after 28 days, confirmed by SEM/EDS. The transformation of sodium aluminosilicate gel into a dense geopolymer matrix was observed, with IR spectra demonstrating the presence of Si–O-(Si/Al) bonds contributing to high compressive strength formulations. Overall, the ABA led to the early formation of the geopolymer 3D network with high compressive strength values.
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Journal of the Australian Ceramic Society since 1965
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