光引发的亲电苯基硒硫酸盐的原位形成

IF 1.4 4区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR
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引用次数: 0

摘要

过硫酸铵是一种温和的氧化剂,能够通过热激活或在剧酸催化下氧化硒硒键。在本文中,我们强调了这一反应可...
本文章由计算机程序翻译,如有差异,请以英文原文为准。
In situ formation of the electrophilic phenylselenenyl sulfate triggered by light
Ammonium persulfate is a mild oxidant capable of oxidizing the selenium-selenium bond through thermal activation or under drastic acid catalysis. In this paper we highlight that this reaction can be activated photochemically, starting from diphenyl diselenide in the absence of any organic or and/or metallic photocatalyst or additive. The protocol was applied to a well-known panel of selenoalkoxylation reactions and the obtained results clearly indicate the involvement of an electrophilic selenium reagent.
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来源期刊
CiteScore
2.60
自引率
7.70%
发文量
103
审稿时长
2.1 months
期刊介绍: Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
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