自由基脱羧：聚合物合成的新兴工具

IF 3.9 2区化学 Q2 POLYMER SCIENCE

Polymer Chemistry Pub Date : 2024-06-25 DOI:10.1039/d4py00267a

Chima Anyaegbu , Gianluca Vidali , Darsan Haridas , Joel F. Hooper

{"title":"自由基脱羧：聚合物合成的新兴工具","authors":"Chima Anyaegbu , Gianluca Vidali , Darsan Haridas , Joel F. Hooper","doi":"10.1039/d4py00267a","DOIUrl":null,"url":null,"abstract":"<div><p>The synthesis of complex and highly functionalised polymer materials requires polymer chemists to search for versatile and efficient new methods for chemical synthesis. Recent years have seen the rise of radical decarboxylation as a novel approach to the initiation, functionalisation, crosslinking and degradation of polymers, allowing access to exciting new materials. This review describes the fundamentals of radical decarboxylation and its use in organic synthesis, along with the increasing application of this approach in polymer synthesis.</p></div>","PeriodicalId":100,"journal":{"name":"Polymer Chemistry","volume":"15 25","pages":"Pages 2537-2547"},"PeriodicalIF":3.9000,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Radical decarboxylation: an emerging tool in polymer synthesis\",\"authors\":\"Chima Anyaegbu , Gianluca Vidali , Darsan Haridas , Joel F. Hooper\",\"doi\":\"10.1039/d4py00267a\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The synthesis of complex and highly functionalised polymer materials requires polymer chemists to search for versatile and efficient new methods for chemical synthesis. Recent years have seen the rise of radical decarboxylation as a novel approach to the initiation, functionalisation, crosslinking and degradation of polymers, allowing access to exciting new materials. This review describes the fundamentals of radical decarboxylation and its use in organic synthesis, along with the increasing application of this approach in polymer synthesis.</p></div>\",\"PeriodicalId\":100,\"journal\":{\"name\":\"Polymer Chemistry\",\"volume\":\"15 25\",\"pages\":\"Pages 2537-2547\"},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2024-06-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1759995424002195\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1759995424002195","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}

引用次数: 0

摘要

要合成复杂的高功能化聚合物材料，聚合物化学家就必须寻找多功能、高效的化学合成新方法。近年来，自由基脱羧法作为一种新型方法在聚合物的引发、官能化、交联和降解等方面崭露头角，使人们有机会获得令人兴奋的新材料。本综述介绍了自由基脱羧的基本原理及其在有机合成中的应用，以及这种方法在聚合物合成中日益广泛的应用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Radical decarboxylation: an emerging tool in polymer synthesis

查看原文本刊更多论文

Radical decarboxylation: an emerging tool in polymer synthesis

The synthesis of complex and highly functionalised polymer materials requires polymer chemists to search for versatile and efficient new methods for chemical synthesis. Recent years have seen the rise of radical decarboxylation as a novel approach to the initiation, functionalisation, crosslinking and degradation of polymers, allowing access to exciting new materials. This review describes the fundamentals of radical decarboxylation and its use in organic synthesis, along with the increasing application of this approach in polymer synthesis.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Polymer Chemistry POLYMER SCIENCE-

CiteScore

8.60

自引率

8.70%

发文量

535

审稿时长

1.7 months

期刊介绍： Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.