Anh Truc Trinh , Anh Son Nguyen , Thu Thuy Thai , Nicolas Caussé , Nadine Pébère
{"title":"锂盐对 2024 铝合金缓蚀作用的比较研究","authors":"Anh Truc Trinh , Anh Son Nguyen , Thu Thuy Thai , Nicolas Caussé , Nadine Pébère","doi":"10.1016/j.apsadv.2024.100606","DOIUrl":null,"url":null,"abstract":"<div><p>In the present work, the corrosion inhibition of AA2024 by lithium salts (nitrate, oxalate and carbonate) is investigated by using both global and local electrochemical techniques. With LiNO<sub>3</sub> (0.1 M), the anodic and cathodic current densities are lower and the impedance values higher by comparison with the results obtained in the presence of 0.1 M Li<sub>2</sub>C<sub>2</sub>O<sub>4</sub> or 0.1 M Li<sub>2</sub>CO<sub>3</sub>. After 20 h of immersion in the electrolyte, SEM observations reveal the formation of thick films on the AA2024 surface in the presence of carbonate or oxalate, whereas a thin and denser film is formed in the presence of nitrate. Specifically, the Li<sub>2</sub>C<sub>2</sub>O<sub>4</sub> addition, by increasing the pH of the electrolyte, induces significant alloy dissolution from the very beginning of immersion which contributes to the growth of a protective layer on the alloy surface, combining lithium, carbonate species and metal cations.</p><p>A self-healing effect by Li<sub>2</sub>C<sub>2</sub>O<sub>4</sub> or Li<sub>2</sub>CO<sub>3</sub> is shown by local impedance measurements on artificial scratches made on a water-based epoxy coating deposited on AA2024 plates, confirming their potential use, as inhibitive species, in organic coatings.</p></div>","PeriodicalId":34303,"journal":{"name":"Applied Surface Science Advances","volume":"21 ","pages":"Article 100606"},"PeriodicalIF":7.5000,"publicationDate":"2024-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666523924000345/pdfft?md5=ea9e65b5604167e9a2995e365264f38e&pid=1-s2.0-S2666523924000345-main.pdf","citationCount":"0","resultStr":"{\"title\":\"A comparative study of lithium salts for the corrosion inhibition of 2024 aluminium alloy\",\"authors\":\"Anh Truc Trinh , Anh Son Nguyen , Thu Thuy Thai , Nicolas Caussé , Nadine Pébère\",\"doi\":\"10.1016/j.apsadv.2024.100606\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In the present work, the corrosion inhibition of AA2024 by lithium salts (nitrate, oxalate and carbonate) is investigated by using both global and local electrochemical techniques. With LiNO<sub>3</sub> (0.1 M), the anodic and cathodic current densities are lower and the impedance values higher by comparison with the results obtained in the presence of 0.1 M Li<sub>2</sub>C<sub>2</sub>O<sub>4</sub> or 0.1 M Li<sub>2</sub>CO<sub>3</sub>. After 20 h of immersion in the electrolyte, SEM observations reveal the formation of thick films on the AA2024 surface in the presence of carbonate or oxalate, whereas a thin and denser film is formed in the presence of nitrate. Specifically, the Li<sub>2</sub>C<sub>2</sub>O<sub>4</sub> addition, by increasing the pH of the electrolyte, induces significant alloy dissolution from the very beginning of immersion which contributes to the growth of a protective layer on the alloy surface, combining lithium, carbonate species and metal cations.</p><p>A self-healing effect by Li<sub>2</sub>C<sub>2</sub>O<sub>4</sub> or Li<sub>2</sub>CO<sub>3</sub> is shown by local impedance measurements on artificial scratches made on a water-based epoxy coating deposited on AA2024 plates, confirming their potential use, as inhibitive species, in organic coatings.</p></div>\",\"PeriodicalId\":34303,\"journal\":{\"name\":\"Applied Surface Science Advances\",\"volume\":\"21 \",\"pages\":\"Article 100606\"},\"PeriodicalIF\":7.5000,\"publicationDate\":\"2024-05-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2666523924000345/pdfft?md5=ea9e65b5604167e9a2995e365264f38e&pid=1-s2.0-S2666523924000345-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Surface Science Advances\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666523924000345\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Surface Science Advances","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666523924000345","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
A comparative study of lithium salts for the corrosion inhibition of 2024 aluminium alloy
In the present work, the corrosion inhibition of AA2024 by lithium salts (nitrate, oxalate and carbonate) is investigated by using both global and local electrochemical techniques. With LiNO3 (0.1 M), the anodic and cathodic current densities are lower and the impedance values higher by comparison with the results obtained in the presence of 0.1 M Li2C2O4 or 0.1 M Li2CO3. After 20 h of immersion in the electrolyte, SEM observations reveal the formation of thick films on the AA2024 surface in the presence of carbonate or oxalate, whereas a thin and denser film is formed in the presence of nitrate. Specifically, the Li2C2O4 addition, by increasing the pH of the electrolyte, induces significant alloy dissolution from the very beginning of immersion which contributes to the growth of a protective layer on the alloy surface, combining lithium, carbonate species and metal cations.
A self-healing effect by Li2C2O4 or Li2CO3 is shown by local impedance measurements on artificial scratches made on a water-based epoxy coating deposited on AA2024 plates, confirming their potential use, as inhibitive species, in organic coatings.