Treatment of phenolic wastewater in an anaerobic fluidized bed microbial fuel cell filled with graphene oxide-macroporous adsorption resin as multifunctional carrier.

A novel graphene oxide-modified resin (graphene oxide-macroporous adsorption resin) was prepared and used as a multifunctional carrier in an anaerobic fluidized bed microbial fuel cell (AFB-MFC) to treat phenolic wastewater (PW). The macroporous adsorption resin (MAR) was used as the carrier, graphene oxide was used as the modified material, the conductive modified resin was prepared by loading graphene oxide (GO) on the resin through chemical reduction. The modified resin particles were characterized by scanning electron microscopy (SEM), Raman spectroscopy (RS), specific surface area and pore structure analysis. Graphene oxide-macroporous adsorption resin special model was established using the Amorphous Cell module in Materials Studio (MS), and the formation mechanism of graphene oxide-macroporous adsorption resin was studied using mean square displacement (MSD) of the force module. Molecular dynamics simulation was used to study the motion law of molecular and atomic dynamics at the interface of graphene oxide-macroporous adsorption resin composites. The strong covalent bond between GO and MAR ensures the stability of GO/MAR. When the modified resin prepared in 3.0 mg/mL GO mixture was used in the AFB-MFC, the COD removal of wastewater was increased by 9.1% to 72.44%, the voltage was increased by 84.04% to 405.8 mV, and power density was increased by 765.44% to 242.67 mW/m².