M. M. Mikhailov, V. A. Goronchko, D. S. Fedosov, A. N. Lapin, S. A. Yuryev
{"title":"Gd2O3 微粉和纳米粉体的光学特性和辐射稳定性比较","authors":"M. M. Mikhailov, V. A. Goronchko, D. S. Fedosov, A. N. Lapin, S. A. Yuryev","doi":"10.1134/S1027451024020101","DOIUrl":null,"url":null,"abstract":"<p>The results of comparative studies of the phase composition, diffuse reflectance spectra, radiation-induced absorption spectra, and the integral absorption coefficient of solar radiation upon irradiation of micro- and nanopowders of gadolinium oxide are presented. To assess the radiation stability of optical properties, the samples were placed in a chamber of an installation simulating space conditions, where diffuse reflection spectra were recorded in the range of 0.2–2.5 μm in a vacuum of 2 × 10<sup>–6</sup> Torr before and after each period of electron irradiation (<i>E</i> = 30 keV, Φ = (1–3) × 10<sup>16</sup> cm<sup>–2</sup>). Micropowders of rare earth elements are used to increase the radiation stability of materials by absorbing free electrons formed in them during irradiation during their transitions from the <i>d</i>- to <i>f</i>-shell. Nanopowders of rare earth elements added to micropowders of various compounds provide an additional mechanism for increasing radiation stability due to the annihilation of primary defects formed during irradiation on nanoparticles. The result obtained in this work is opposite to these mechanisms—the radiation stability of a micropowder is significantly (more than 4 times) higher compared to a nanopowder due to more intense absorption in the ultraviolet region for the nanopowder caused by their own defects. The paper gives an explanation of the results obtained.</p>","PeriodicalId":671,"journal":{"name":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","volume":"18 2","pages":"293 - 299"},"PeriodicalIF":0.5000,"publicationDate":"2024-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Comparison of Optical Properties and Radiation Stability of Gd2O3 Micro- and Nanopowders\",\"authors\":\"M. M. Mikhailov, V. A. Goronchko, D. S. Fedosov, A. N. Lapin, S. A. Yuryev\",\"doi\":\"10.1134/S1027451024020101\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The results of comparative studies of the phase composition, diffuse reflectance spectra, radiation-induced absorption spectra, and the integral absorption coefficient of solar radiation upon irradiation of micro- and nanopowders of gadolinium oxide are presented. To assess the radiation stability of optical properties, the samples were placed in a chamber of an installation simulating space conditions, where diffuse reflection spectra were recorded in the range of 0.2–2.5 μm in a vacuum of 2 × 10<sup>–6</sup> Torr before and after each period of electron irradiation (<i>E</i> = 30 keV, Φ = (1–3) × 10<sup>16</sup> cm<sup>–2</sup>). Micropowders of rare earth elements are used to increase the radiation stability of materials by absorbing free electrons formed in them during irradiation during their transitions from the <i>d</i>- to <i>f</i>-shell. Nanopowders of rare earth elements added to micropowders of various compounds provide an additional mechanism for increasing radiation stability due to the annihilation of primary defects formed during irradiation on nanoparticles. The result obtained in this work is opposite to these mechanisms—the radiation stability of a micropowder is significantly (more than 4 times) higher compared to a nanopowder due to more intense absorption in the ultraviolet region for the nanopowder caused by their own defects. The paper gives an explanation of the results obtained.</p>\",\"PeriodicalId\":671,\"journal\":{\"name\":\"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques\",\"volume\":\"18 2\",\"pages\":\"293 - 299\"},\"PeriodicalIF\":0.5000,\"publicationDate\":\"2024-05-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1027451024020101\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S1027451024020101","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
Comparison of Optical Properties and Radiation Stability of Gd2O3 Micro- and Nanopowders
The results of comparative studies of the phase composition, diffuse reflectance spectra, radiation-induced absorption spectra, and the integral absorption coefficient of solar radiation upon irradiation of micro- and nanopowders of gadolinium oxide are presented. To assess the radiation stability of optical properties, the samples were placed in a chamber of an installation simulating space conditions, where diffuse reflection spectra were recorded in the range of 0.2–2.5 μm in a vacuum of 2 × 10–6 Torr before and after each period of electron irradiation (E = 30 keV, Φ = (1–3) × 1016 cm–2). Micropowders of rare earth elements are used to increase the radiation stability of materials by absorbing free electrons formed in them during irradiation during their transitions from the d- to f-shell. Nanopowders of rare earth elements added to micropowders of various compounds provide an additional mechanism for increasing radiation stability due to the annihilation of primary defects formed during irradiation on nanoparticles. The result obtained in this work is opposite to these mechanisms—the radiation stability of a micropowder is significantly (more than 4 times) higher compared to a nanopowder due to more intense absorption in the ultraviolet region for the nanopowder caused by their own defects. The paper gives an explanation of the results obtained.
期刊介绍：
Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques publishes original articles on the topical problems of solid-state physics, materials science, experimental techniques, condensed media, nanostructures, surfaces of thin films, and phase boundaries: geometric and energetical structures of surfaces, the methods of computer simulations; physical and chemical properties and their changes upon radiation and other treatments; the methods of studies of films and surface layers of crystals (XRD, XPS, synchrotron radiation, neutron and electron diffraction, electron microscopic, scanning tunneling microscopic, atomic force microscopic studies, and other methods that provide data on the surfaces and thin films). Articles related to the methods and technics of structure studies are the focus of the journal. The journal accepts manuscripts of regular articles and reviews in English or Russian language from authors of all countries. All manuscripts are peer-reviewed.
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