{"title":"利用汞同位素和痕量元素制约华南奥陶纪香泉碲矿床的起源","authors":"Lei Meng , Mei-Fu Zhou , Wei Terry Chen","doi":"10.1016/j.jseaes.2024.106168","DOIUrl":null,"url":null,"abstract":"<div><p>Sediment-hosted stratiform sulfide (SHSS) deposits commonly contain large amounts of strategic metals, such as Tl, Hg, Cd, Ge and Ga, however, sources of these metals remain debate. Here we present new elemental and Hg isotopic data to constrain the metal sources for the Xiangquan Tl deposit (South China), a unique SHSS deposit with 250 t Tl at an average grade of 928 ppm. Stratiform pyrite orebodies are hosted in the Ordovician marine sedimentary succession of mostly limestone with minor mudstone. Pyrite, the dominant ore mineral, is rich in Hg (up to 1360 ppm). Bulk ores and pyrite separates from this deposit have significant variations of δ<sup>202</sup>Hg (−5.48 to −0.65 ‰) and Δ<sup>199</sup>Hg (−0.01 to 0.36 ‰). The Δ<sup>199</sup>Hg values are mostly positive, similar to those of seawater and marine sediments. Ore petrography, trace element enrichment coefficients, rare earth element patterns, Re-Os ages (478 ± 33 Ma) and S isotope compositions of pyrite indicate that Hg and other metals were derived from hydrothermal fluids venting at the seafloor. We suggest that the ore-forming fluids of the Xiangquan deposit were predominantly originated from large-scale circulation of evolved seawater, which leached Hg and Tl from the marine country rocks. These metal-rich fluids migrated upward, vented to the seafloor, and mixed with anoxic H<sub>2</sub>S-rich seawater to precipitate Hg- and Tl-rich pyrite. Our study highlights that the combined application of Hg isotopes and trace elements could be used to trace the sources of metals in hydrothermal ore deposits such as SHSS deposits.</p></div>","PeriodicalId":50253,"journal":{"name":"Journal of Asian Earth Sciences","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Using Hg isotopes and trace elements to constrain the origin of the Ordovician Xiangquan Tl deposit, South China\",\"authors\":\"Lei Meng , Mei-Fu Zhou , Wei Terry Chen\",\"doi\":\"10.1016/j.jseaes.2024.106168\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Sediment-hosted stratiform sulfide (SHSS) deposits commonly contain large amounts of strategic metals, such as Tl, Hg, Cd, Ge and Ga, however, sources of these metals remain debate. Here we present new elemental and Hg isotopic data to constrain the metal sources for the Xiangquan Tl deposit (South China), a unique SHSS deposit with 250 t Tl at an average grade of 928 ppm. Stratiform pyrite orebodies are hosted in the Ordovician marine sedimentary succession of mostly limestone with minor mudstone. Pyrite, the dominant ore mineral, is rich in Hg (up to 1360 ppm). Bulk ores and pyrite separates from this deposit have significant variations of δ<sup>202</sup>Hg (−5.48 to −0.65 ‰) and Δ<sup>199</sup>Hg (−0.01 to 0.36 ‰). The Δ<sup>199</sup>Hg values are mostly positive, similar to those of seawater and marine sediments. Ore petrography, trace element enrichment coefficients, rare earth element patterns, Re-Os ages (478 ± 33 Ma) and S isotope compositions of pyrite indicate that Hg and other metals were derived from hydrothermal fluids venting at the seafloor. We suggest that the ore-forming fluids of the Xiangquan deposit were predominantly originated from large-scale circulation of evolved seawater, which leached Hg and Tl from the marine country rocks. These metal-rich fluids migrated upward, vented to the seafloor, and mixed with anoxic H<sub>2</sub>S-rich seawater to precipitate Hg- and Tl-rich pyrite. Our study highlights that the combined application of Hg isotopes and trace elements could be used to trace the sources of metals in hydrothermal ore deposits such as SHSS deposits.</p></div>\",\"PeriodicalId\":50253,\"journal\":{\"name\":\"Journal of Asian Earth Sciences\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-05-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Asian Earth Sciences\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1367912024001639\",\"RegionNum\":3,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GEOSCIENCES, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Asian Earth Sciences","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1367912024001639","RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
Using Hg isotopes and trace elements to constrain the origin of the Ordovician Xiangquan Tl deposit, South China
Sediment-hosted stratiform sulfide (SHSS) deposits commonly contain large amounts of strategic metals, such as Tl, Hg, Cd, Ge and Ga, however, sources of these metals remain debate. Here we present new elemental and Hg isotopic data to constrain the metal sources for the Xiangquan Tl deposit (South China), a unique SHSS deposit with 250 t Tl at an average grade of 928 ppm. Stratiform pyrite orebodies are hosted in the Ordovician marine sedimentary succession of mostly limestone with minor mudstone. Pyrite, the dominant ore mineral, is rich in Hg (up to 1360 ppm). Bulk ores and pyrite separates from this deposit have significant variations of δ202Hg (−5.48 to −0.65 ‰) and Δ199Hg (−0.01 to 0.36 ‰). The Δ199Hg values are mostly positive, similar to those of seawater and marine sediments. Ore petrography, trace element enrichment coefficients, rare earth element patterns, Re-Os ages (478 ± 33 Ma) and S isotope compositions of pyrite indicate that Hg and other metals were derived from hydrothermal fluids venting at the seafloor. We suggest that the ore-forming fluids of the Xiangquan deposit were predominantly originated from large-scale circulation of evolved seawater, which leached Hg and Tl from the marine country rocks. These metal-rich fluids migrated upward, vented to the seafloor, and mixed with anoxic H2S-rich seawater to precipitate Hg- and Tl-rich pyrite. Our study highlights that the combined application of Hg isotopes and trace elements could be used to trace the sources of metals in hydrothermal ore deposits such as SHSS deposits.
期刊介绍:
Journal of Asian Earth Sciences has an open access mirror journal Journal of Asian Earth Sciences: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
The Journal of Asian Earth Sciences is an international interdisciplinary journal devoted to all aspects of research related to the solid Earth Sciences of Asia. The Journal publishes high quality, peer-reviewed scientific papers on the regional geology, tectonics, geochemistry and geophysics of Asia. It will be devoted primarily to research papers but short communications relating to new developments of broad interest, reviews and book reviews will also be included. Papers must have international appeal and should present work of more than local significance.
The scope includes deep processes of the Asian continent and its adjacent oceans; seismology and earthquakes; orogeny, magmatism, metamorphism and volcanism; growth, deformation and destruction of the Asian crust; crust-mantle interaction; evolution of life (early life, biostratigraphy, biogeography and mass-extinction); fluids, fluxes and reservoirs of mineral and energy resources; surface processes (weathering, erosion, transport and deposition of sediments) and resulting geomorphology; and the response of the Earth to global climate change as viewed within the Asian continent and surrounding oceans.