Yathavan Subramanian , Anitha Dhanasekaran , Yen Pei Fu , Minh Thang Le , Lukman Ahmed Omeiza , ABM Kamrul Hasan , John T.S. Irvine , Abul K. Azad
{"title":"揭示异阴离子碳氧钛光催化剂在水源中解毒 SARS-Cov-2 抗原快速检测试剂盒试剂溶液的潜力","authors":"Yathavan Subramanian , Anitha Dhanasekaran , Yen Pei Fu , Minh Thang Le , Lukman Ahmed Omeiza , ABM Kamrul Hasan , John T.S. Irvine , Abul K. Azad","doi":"10.1016/j.kjs.2024.100241","DOIUrl":null,"url":null,"abstract":"<div><p>In the last few years, the COVID-19 pandemic has increased the usage of antigen rapid test (ART) kits and improper disposal of these kits has led to the mixing of toxic chemical compounds present in the ART reagent solution container into drinking water sources. When consumed with drinking water, these compounds can be harmful and toxic to both humans and aquatic life. Therefore, this research presents a study on the photocatalytic degradation of the Antigen Rapid Test-Reagent solution (ART-RS) using a single-phase titanium oxycarbide - TiO<sub>0.25</sub> C<sub>0.75</sub> (TiOC) photocatalyst synthesized through a solid-state reaction. The synthesized samples were studied using various characterization tools to analyze their structural, morphological, and optical characteristics. In the photocatalytic experiment, it was found that the synthesized titanium oxycarbide photocatalyst exhibited superior ART-RS degradation efficiency of 77% compared to commercial titanium dioxide (22%). The improved photocatalytic degradation efficiency of ART-RS is attributed to a combination of several factors. These factors include a narrower band gap, more efficient charge transfer kinetics, enhanced absorption of visible light, and an upward shift of the valence band (VB) edge in titanium oxycarbide. These collective effects contribute to the enhanced ART-RS photocatalytic degradation activity.</p></div>","PeriodicalId":17848,"journal":{"name":"Kuwait Journal of Science","volume":"51 3","pages":"Article 100241"},"PeriodicalIF":1.2000,"publicationDate":"2024-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S230741082400066X/pdfft?md5=24ae3d959fadfa6e26f8e68b8a232661&pid=1-s2.0-S230741082400066X-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Unraveling the potential of heteroanionic titanium oxycarbide photocatalysts for detoxifying SARS-Cov-2 antigen rapid test kit reagent solution in water sources\",\"authors\":\"Yathavan Subramanian , Anitha Dhanasekaran , Yen Pei Fu , Minh Thang Le , Lukman Ahmed Omeiza , ABM Kamrul Hasan , John T.S. Irvine , Abul K. Azad\",\"doi\":\"10.1016/j.kjs.2024.100241\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In the last few years, the COVID-19 pandemic has increased the usage of antigen rapid test (ART) kits and improper disposal of these kits has led to the mixing of toxic chemical compounds present in the ART reagent solution container into drinking water sources. When consumed with drinking water, these compounds can be harmful and toxic to both humans and aquatic life. Therefore, this research presents a study on the photocatalytic degradation of the Antigen Rapid Test-Reagent solution (ART-RS) using a single-phase titanium oxycarbide - TiO<sub>0.25</sub> C<sub>0.75</sub> (TiOC) photocatalyst synthesized through a solid-state reaction. The synthesized samples were studied using various characterization tools to analyze their structural, morphological, and optical characteristics. In the photocatalytic experiment, it was found that the synthesized titanium oxycarbide photocatalyst exhibited superior ART-RS degradation efficiency of 77% compared to commercial titanium dioxide (22%). The improved photocatalytic degradation efficiency of ART-RS is attributed to a combination of several factors. These factors include a narrower band gap, more efficient charge transfer kinetics, enhanced absorption of visible light, and an upward shift of the valence band (VB) edge in titanium oxycarbide. These collective effects contribute to the enhanced ART-RS photocatalytic degradation activity.</p></div>\",\"PeriodicalId\":17848,\"journal\":{\"name\":\"Kuwait Journal of Science\",\"volume\":\"51 3\",\"pages\":\"Article 100241\"},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2024-05-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S230741082400066X/pdfft?md5=24ae3d959fadfa6e26f8e68b8a232661&pid=1-s2.0-S230741082400066X-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Kuwait Journal of Science\",\"FirstCategoryId\":\"103\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S230741082400066X\",\"RegionNum\":4,\"RegionCategory\":\"综合性期刊\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MULTIDISCIPLINARY SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Kuwait Journal of Science","FirstCategoryId":"103","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S230741082400066X","RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
Unraveling the potential of heteroanionic titanium oxycarbide photocatalysts for detoxifying SARS-Cov-2 antigen rapid test kit reagent solution in water sources
In the last few years, the COVID-19 pandemic has increased the usage of antigen rapid test (ART) kits and improper disposal of these kits has led to the mixing of toxic chemical compounds present in the ART reagent solution container into drinking water sources. When consumed with drinking water, these compounds can be harmful and toxic to both humans and aquatic life. Therefore, this research presents a study on the photocatalytic degradation of the Antigen Rapid Test-Reagent solution (ART-RS) using a single-phase titanium oxycarbide - TiO0.25 C0.75 (TiOC) photocatalyst synthesized through a solid-state reaction. The synthesized samples were studied using various characterization tools to analyze their structural, morphological, and optical characteristics. In the photocatalytic experiment, it was found that the synthesized titanium oxycarbide photocatalyst exhibited superior ART-RS degradation efficiency of 77% compared to commercial titanium dioxide (22%). The improved photocatalytic degradation efficiency of ART-RS is attributed to a combination of several factors. These factors include a narrower band gap, more efficient charge transfer kinetics, enhanced absorption of visible light, and an upward shift of the valence band (VB) edge in titanium oxycarbide. These collective effects contribute to the enhanced ART-RS photocatalytic degradation activity.
期刊介绍:
Kuwait Journal of Science (KJS) is indexed and abstracted by major publishing houses such as Chemical Abstract, Science Citation Index, Current contents, Mathematics Abstract, Micribiological Abstracts etc. KJS publishes peer-review articles in various fields of Science including Mathematics, Computer Science, Physics, Statistics, Biology, Chemistry and Earth & Environmental Sciences. In addition, it also aims to bring the results of scientific research carried out under a variety of intellectual traditions and organizations to the attention of specialized scholarly readership. As such, the publisher expects the submission of original manuscripts which contain analysis and solutions about important theoretical, empirical and normative issues.