{"title":"开发用于光催化 H2O2 生产的聚合氮化碳。","authors":"Dandan Zheng, Yahan Wu, Xintuo Yang, Sibo Wang, Yuanxing Fang","doi":"10.1002/cssc.202400528","DOIUrl":null,"url":null,"abstract":"<p><p>Hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) plays a crucial role in various applications, such as green oxidation processes and the production of high-quality fuels. Currently, H<sub>2</sub>O<sub>2</sub> is primarily manufactured using the indirect anthraquinone method, known for its significant energy consumption and the generation of intensive by-products. Extensive research has been conducted on the photocatalytic production of H<sub>2</sub>O<sub>2</sub> via oxygen reduction reaction (ORR), with polymeric carbon nitride (PCN) emerging as a promising catalyst for this conversion. This review article is organized around two approaches. The first part main consists of the chemical optimization of the PCN structure, while the second focuses on the physical integration of PCN with other functional materials. The objective is to clarify the correlation between the physicochemical properties of PCN photocatalysts and their effectiveness in H<sub>2</sub>O<sub>2</sub> production. Through a thorough review and analysis of the findings, this article seeks to stimulate new insights and achievements, not only in the domain of H<sub>2</sub>O<sub>2</sub> production via ORR but also in other redox reactions.</p>","PeriodicalId":149,"journal":{"name":"ChemSusChem","volume":null,"pages":null},"PeriodicalIF":7.5000,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Developing Polymeric Carbon Nitrides for Photocatalytic H<sub>2</sub>O<sub>2</sub> Production.\",\"authors\":\"Dandan Zheng, Yahan Wu, Xintuo Yang, Sibo Wang, Yuanxing Fang\",\"doi\":\"10.1002/cssc.202400528\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) plays a crucial role in various applications, such as green oxidation processes and the production of high-quality fuels. Currently, H<sub>2</sub>O<sub>2</sub> is primarily manufactured using the indirect anthraquinone method, known for its significant energy consumption and the generation of intensive by-products. Extensive research has been conducted on the photocatalytic production of H<sub>2</sub>O<sub>2</sub> via oxygen reduction reaction (ORR), with polymeric carbon nitride (PCN) emerging as a promising catalyst for this conversion. This review article is organized around two approaches. The first part main consists of the chemical optimization of the PCN structure, while the second focuses on the physical integration of PCN with other functional materials. The objective is to clarify the correlation between the physicochemical properties of PCN photocatalysts and their effectiveness in H<sub>2</sub>O<sub>2</sub> production. Through a thorough review and analysis of the findings, this article seeks to stimulate new insights and achievements, not only in the domain of H<sub>2</sub>O<sub>2</sub> production via ORR but also in other redox reactions.</p>\",\"PeriodicalId\":149,\"journal\":{\"name\":\"ChemSusChem\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":7.5000,\"publicationDate\":\"2024-10-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemSusChem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/cssc.202400528\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/6/10 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemSusChem","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/cssc.202400528","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/6/10 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Developing Polymeric Carbon Nitrides for Photocatalytic H2O2 Production.
Hydrogen peroxide (H2O2) plays a crucial role in various applications, such as green oxidation processes and the production of high-quality fuels. Currently, H2O2 is primarily manufactured using the indirect anthraquinone method, known for its significant energy consumption and the generation of intensive by-products. Extensive research has been conducted on the photocatalytic production of H2O2 via oxygen reduction reaction (ORR), with polymeric carbon nitride (PCN) emerging as a promising catalyst for this conversion. This review article is organized around two approaches. The first part main consists of the chemical optimization of the PCN structure, while the second focuses on the physical integration of PCN with other functional materials. The objective is to clarify the correlation between the physicochemical properties of PCN photocatalysts and their effectiveness in H2O2 production. Through a thorough review and analysis of the findings, this article seeks to stimulate new insights and achievements, not only in the domain of H2O2 production via ORR but also in other redox reactions.
期刊介绍:
ChemSusChem
Impact Factor (2016): 7.226
Scope:
Interdisciplinary journal
Focuses on research at the interface of chemistry and sustainability
Features the best research on sustainability and energy
Areas Covered:
Chemistry
Materials Science
Chemical Engineering
Biotechnology