研究 TiO2 纳米粒子对干法和湿法丝瓜络-环氧树脂纳米复合材料拉伸性能和热稳定性的影响

IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
K. Anbukarasi, D. Mala, N. Senthilkumar, S. Imran Hussain, S. Kalaiselvam
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引用次数: 0

摘要

背景:最近,人们在了解天然纤维聚合物复合材料的效率方面取得了进展。为了提高天然纤维聚合物复合材料在含水环境中的特性,人们使用了纳米 TiO2 粒子来改善其在该领域的性能。方法:将这些纳米粒子以 1%、3% 和 5%的体积分数填充到松软环氧成分中。采用 X 射线衍射和傅立叶变换红外光谱相结合的方法进行结构检测。场发射扫描电子显微镜捕捉了纳米粒子的分布情况。结果显示结果表明,干法纳米复合材料的拉伸强度和模量分别比环氧树脂和 40 vol% 的凝胶-环氧 [E/L] 复合材料提高了 74%、13%、137% 和 50%。在湿纳米复合材料中,拉伸强度和模量的最大降幅分别为 27.4% 和 16.54%。纳米复合材料的吸水率和厚度膨胀率分别降低了 98% 和 91.8%。这些纳米复合材料的起始温度分布在 379-393°C 之间,最大残炭率为 38%:为了均匀分散纳米粒子,使用了超声波发生器;为了制造纳米复合材料,采用了手糊法。根据 ASTM 准则对复合材料进行测试:残留物百分比的增加表明环氧树脂的阻燃性能有效,热稳定性得到改善,吸水性降低[约 2%],湿复合材料的拉伸性能保持 95%。这些结果为改进纳米复合材料在汽车领域的应用提供了数据支持:干法 nTiO2 纳米复合材料的拉伸强度和模量分别比环氧树脂复合材料和 40 vol% 的松香-环氧树脂 (E/L) 复合材料提高了 74% 和 13%,137% 和 50%。在湿纳米复合材料中,拉伸强度和模量的最大降幅分别为 27.4% 和 16.54%。纳米复合材料的吸水率和厚度膨胀率分别降低了 98% 和 91.8%:- nTiO2 填充的凝胶-环氧纳米复合材料的吸水率较低。因为 nTiO2 有效地降低了丝瓜纤维的亲水性:生成的丝瓜-环氧纳米复合材料可作为汽车内饰中使用的石油基塑料的环保型替代品
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of TiO2 Nanoparticles Influence on Tensile Properties and Thermal Stability of Dry and Wet Luffa-Epoxy Nanocomposites
Background: Recently, progress has been made toward understanding the efficiency of polymer composites with natural fibres. With the hope of enhancing the characteristics of polymer composites supplemented with natural fibres in a watery environment, TiO2 nanoparticles have been used to improve their performance in the field. Method: These nanoparticles were filled in luffa-epoxy components at 1, 3, and 5 % volume fractions. A combination of x-ray diffraction and Fourier transform infrared spectroscopy was utilized to conduct the structural examinations. The nanoparticle spread was captured by field emission scanning electron microscopy. Result: Results show that dry nanocomposite's tensile strength and modulus have increased by 74% and, 13%, 137%, and 50% compared with epoxy and 40 vol% luffa-epoxy [E/L] composites, respectively. In wet nanocomposites, maximum reduction in tensile strength and modulus were observed as 27.4% and 16.54%, respectively. The diminished water absorption and thickness swelling percentage of nanocomposites were recorded as 98% and 91.8%, respectively. The onset temperature of these nanocomposites was scattered in the range of 379-393°C, with a maximum char residue of 38%. method: For uniform dispersal of nanoparticles, an ultrasonicator is used, and for the fabrication of nanocomposite, hand layup is adopted. Testing of composites is done as per the ASTM guidelines Conclusion: The increase in the percentage of residue indicates the effectiveness of epoxy's flame retardant, improved thermal stability, diminished water absorption [approximately 2%], and 95% retention of wet composites' tensile properties. These results provided data support for improving the application of nanocomposites in the automobile field. result: The tensile strength and modulus of dry nTiO2 nanocomposite have increased by 74% and 13%, 137% and 50% compared with epoxy and 40 vol% luffa-epoxy (E/L) composites, respectively. In wet nanocomposites, maximum reduction in tensile strength and modulus were observed as 27.4% and 16.54%, respectively. Diminished water absorption and thickness swelling percentage of nanocomposites were recorded as 98% and 91.8%, respectively conclusion: • nTiO2-filled luffa-epoxy nanocomposites have a low percentage of water absorption. Because the nTiO2 effectively contributed to decreasing the hydrophilic nature of luffa fibers. other: The generated luffa-epoxy nanocomposites could serve as an eco-friendly substitute for petroleum-based plastics used in car interiors
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来源期刊
Recent Patents on Nanotechnology
Recent Patents on Nanotechnology NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
4.70
自引率
10.00%
发文量
50
审稿时长
3 months
期刊介绍: Recent Patents on Nanotechnology publishes full-length/mini reviews and research articles that reflect or deal with studies in relation to a patent, application of reported patents in a study, discussion of comparison of results regarding application of a given patent, etc., and also guest edited thematic issues on recent patents in the field of nanotechnology. A selection of important and recent patents on nanotechnology is also included in the journal. The journal is essential reading for all researchers involved in nanotechnology.
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