用 [TBA][P(SiCl3)2]温和且无催化剂地磷化异氰酸酯以合成膦甲酰胺

IF 2.8 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2024-07-01 DOI:10.1002/ajoc.202400178

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引用次数: 0

摘要

本文介绍了利用 [TBA][P(SiCl3)2]作为 P 源合成膦甲酰胺的过程。合成过程包括 [TBA][P(SiCl3)2]与异氰酸酯的反应。这些化合物是异氰酸酯随后磷化的高效试剂，可生成膦（三碳酰胺）。该反应在温和直接的条件下迅速进行，因此适用于多种市售异氰酸酯。

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Mild and Catalyst‐Free Phosphination of Isocyanates with [TBA][P(SiCl3)2] for the Synthesis of Phosphinecarboxamides

A procedure utilizing [TBA][P(SiCl₃)₂] as P source for the synthesis of phosphinecarboxamides is presented. The synthesis involves the reaction of [TBA][P(SiCl₃)₂] with isocyanates. These compounds act as highly effective reagents for the subsequent phosphination of isocyanates, leading to the formation of phosphine(triscarboxamides). This reaction proceeds swiftly under mild and straightforward conditions, making it suitable for a wide range of commercially available isocyanates.

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来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.