{"title":"用于大容积塞贝克量热计的卷积去噪技术","authors":"Wu-Shou Zhang","doi":"10.1016/j.tca.2024.179760","DOIUrl":null,"url":null,"abstract":"<div><p>Ambient temperature fluctuations can affect the thermal noise and sensitivity of a large-volume Seebeck calorimeter. This paper proposes that a reference cell considerably smaller than the sample cell in the apparatus can effectively neutralize this noise. It is found that the thermal signals from both the reference and sample cells exhibit a convolution relationship. By deconvolving two distinct thermal pulses generated by abrupt changes in cooling fluid temperature, one from the reference cell and one from the sample cell, a corresponding response function is derived. And using this function, the noise is canceled out by subtracting the convoluted signal of the reference cell from that of the sample cell during isothermal calorimetry. Experimentally, utilizing this technique with two calorimeters, one with a 17.6-liter capacity and the other with a 27-liter capacity, has been shown to reduce noise by at least 5 % and 6 % from their initial values, respectively.</p></div>","PeriodicalId":23058,"journal":{"name":"Thermochimica Acta","volume":null,"pages":null},"PeriodicalIF":3.1000,"publicationDate":"2024-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Convolutional denoising for large-volume Seebeck calorimeter\",\"authors\":\"Wu-Shou Zhang\",\"doi\":\"10.1016/j.tca.2024.179760\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Ambient temperature fluctuations can affect the thermal noise and sensitivity of a large-volume Seebeck calorimeter. This paper proposes that a reference cell considerably smaller than the sample cell in the apparatus can effectively neutralize this noise. It is found that the thermal signals from both the reference and sample cells exhibit a convolution relationship. By deconvolving two distinct thermal pulses generated by abrupt changes in cooling fluid temperature, one from the reference cell and one from the sample cell, a corresponding response function is derived. And using this function, the noise is canceled out by subtracting the convoluted signal of the reference cell from that of the sample cell during isothermal calorimetry. Experimentally, utilizing this technique with two calorimeters, one with a 17.6-liter capacity and the other with a 27-liter capacity, has been shown to reduce noise by at least 5 % and 6 % from their initial values, respectively.</p></div>\",\"PeriodicalId\":23058,\"journal\":{\"name\":\"Thermochimica Acta\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2024-04-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Thermochimica Acta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0040603124000996\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Thermochimica Acta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040603124000996","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Convolutional denoising for large-volume Seebeck calorimeter
Ambient temperature fluctuations can affect the thermal noise and sensitivity of a large-volume Seebeck calorimeter. This paper proposes that a reference cell considerably smaller than the sample cell in the apparatus can effectively neutralize this noise. It is found that the thermal signals from both the reference and sample cells exhibit a convolution relationship. By deconvolving two distinct thermal pulses generated by abrupt changes in cooling fluid temperature, one from the reference cell and one from the sample cell, a corresponding response function is derived. And using this function, the noise is canceled out by subtracting the convoluted signal of the reference cell from that of the sample cell during isothermal calorimetry. Experimentally, utilizing this technique with two calorimeters, one with a 17.6-liter capacity and the other with a 27-liter capacity, has been shown to reduce noise by at least 5 % and 6 % from their initial values, respectively.
期刊介绍:
Thermochimica Acta publishes original research contributions covering all aspects of thermoanalytical and calorimetric methods and their application to experimental chemistry, physics, biology and engineering. The journal aims to span the whole range from fundamental research to practical application.
The journal focuses on the research that advances physical and analytical science of thermal phenomena. Therefore, the manuscripts are expected to provide important insights into the thermal phenomena studied or to propose significant improvements of analytical or computational techniques employed in thermal studies. Manuscripts that report the results of routine thermal measurements are not suitable for publication in Thermochimica Acta.
The journal particularly welcomes papers from newly emerging areas as well as from the traditional strength areas:
- New and improved instrumentation and methods
- Thermal properties and behavior of materials
- Kinetics of thermally stimulated processes