{"title":"利用黑磷纳米片和二乙基膦酸铝体系提高热塑性聚(醚酯)弹性体的防火安全性","authors":"Shijie Zhang, Jiaxuan Li, Jiuhong Liu, Jinpeng Song, Qing Yu, Liang Song, Guiqing Cheng, Zhongwei Wang, Yuxi Han","doi":"10.1002/vnl.22108","DOIUrl":null,"url":null,"abstract":"<div>\n \n \n <section>\n \n <p>Thermoplastic poly(ether ester) elastomer (TPEE) is a highly flammable material with severe melt-dropping, which greatly limits its range of applications. Here, black phosphorus nanosheets (BPs) and aluminum diethylphosphinate (ADP) were used to improve the fire safety of TPEE for the first time. Results demonstrated that ADP/BPs as a synergistic combination exhibits good dispersity and excellent flame retardancy, also has minimal negative effects on the mechanical performances of the TPEE composites. By comparing TPEE/ADP-22 and TPEE/ADP-10/BPs-4, the introduction of BPs significantly reduced the addition of ADP while keeping the material at the higher vertical burning grade, ~54.5% reduction in ADP usage. Compared with neat TPEE, TPEE/ADP-10/BPs-4 fulfilled V-0 level, avoided dripping, and the limiting oxygen index value increased to 34.0%. Moreover, TPEE/ADP-10/BPs-4 performed the best in cone calorimetry test, both the peak heat release rate and total heat release reduced the largest, by 44.2% and 25.3%, respectively. The detailed studies of the flame-retardant mechanism found that ADP/BPs showed the fire-retardant impact of the condensed phase and gaseous phase. This work expands BPs in the flame-retardant application and could facilitate to prepare the anti-dripping flame-resistant TPEE.</p>\n </section>\n \n <section>\n \n <h3> Highlights</h3>\n \n <div>\n <ul>\n \n <li>BPs as an efficient flame retardant were added into TPEE for the first time.</li>\n \n <li>ADP/BPs as a synergistic combination has an excellent fire-retardant effect.</li>\n \n <li>The introduction of BPs significantly reduced the addition of ADP.</li>\n \n <li>TPEE/ADP-10/BPs-4 showed the highest FPI and the lowest FGI.</li>\n \n <li>ADP/BPs has lowest negative effects on the mechanical performances of matrix.</li>\n </ul>\n </div>\n </section>\n </div>","PeriodicalId":17662,"journal":{"name":"Journal of Vinyl & Additive Technology","volume":"30 5","pages":"1139-1152"},"PeriodicalIF":3.8000,"publicationDate":"2024-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Improving fire safety of thermoplastic poly(ether ester) elastomer by black phosphorus nanosheets and aluminum diethylphosphinate system\",\"authors\":\"Shijie Zhang, Jiaxuan Li, Jiuhong Liu, Jinpeng Song, Qing Yu, Liang Song, Guiqing Cheng, Zhongwei Wang, Yuxi Han\",\"doi\":\"10.1002/vnl.22108\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n \\n <section>\\n \\n <p>Thermoplastic poly(ether ester) elastomer (TPEE) is a highly flammable material with severe melt-dropping, which greatly limits its range of applications. Here, black phosphorus nanosheets (BPs) and aluminum diethylphosphinate (ADP) were used to improve the fire safety of TPEE for the first time. Results demonstrated that ADP/BPs as a synergistic combination exhibits good dispersity and excellent flame retardancy, also has minimal negative effects on the mechanical performances of the TPEE composites. By comparing TPEE/ADP-22 and TPEE/ADP-10/BPs-4, the introduction of BPs significantly reduced the addition of ADP while keeping the material at the higher vertical burning grade, ~54.5% reduction in ADP usage. Compared with neat TPEE, TPEE/ADP-10/BPs-4 fulfilled V-0 level, avoided dripping, and the limiting oxygen index value increased to 34.0%. Moreover, TPEE/ADP-10/BPs-4 performed the best in cone calorimetry test, both the peak heat release rate and total heat release reduced the largest, by 44.2% and 25.3%, respectively. The detailed studies of the flame-retardant mechanism found that ADP/BPs showed the fire-retardant impact of the condensed phase and gaseous phase. This work expands BPs in the flame-retardant application and could facilitate to prepare the anti-dripping flame-resistant TPEE.</p>\\n </section>\\n \\n <section>\\n \\n <h3> Highlights</h3>\\n \\n <div>\\n <ul>\\n \\n <li>BPs as an efficient flame retardant were added into TPEE for the first time.</li>\\n \\n <li>ADP/BPs as a synergistic combination has an excellent fire-retardant effect.</li>\\n \\n <li>The introduction of BPs significantly reduced the addition of ADP.</li>\\n \\n <li>TPEE/ADP-10/BPs-4 showed the highest FPI and the lowest FGI.</li>\\n \\n <li>ADP/BPs has lowest negative effects on the mechanical performances of matrix.</li>\\n </ul>\\n </div>\\n </section>\\n </div>\",\"PeriodicalId\":17662,\"journal\":{\"name\":\"Journal of Vinyl & Additive Technology\",\"volume\":\"30 5\",\"pages\":\"1139-1152\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-04-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Vinyl & Additive Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/vnl.22108\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Vinyl & Additive Technology","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/vnl.22108","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Improving fire safety of thermoplastic poly(ether ester) elastomer by black phosphorus nanosheets and aluminum diethylphosphinate system
Thermoplastic poly(ether ester) elastomer (TPEE) is a highly flammable material with severe melt-dropping, which greatly limits its range of applications. Here, black phosphorus nanosheets (BPs) and aluminum diethylphosphinate (ADP) were used to improve the fire safety of TPEE for the first time. Results demonstrated that ADP/BPs as a synergistic combination exhibits good dispersity and excellent flame retardancy, also has minimal negative effects on the mechanical performances of the TPEE composites. By comparing TPEE/ADP-22 and TPEE/ADP-10/BPs-4, the introduction of BPs significantly reduced the addition of ADP while keeping the material at the higher vertical burning grade, ~54.5% reduction in ADP usage. Compared with neat TPEE, TPEE/ADP-10/BPs-4 fulfilled V-0 level, avoided dripping, and the limiting oxygen index value increased to 34.0%. Moreover, TPEE/ADP-10/BPs-4 performed the best in cone calorimetry test, both the peak heat release rate and total heat release reduced the largest, by 44.2% and 25.3%, respectively. The detailed studies of the flame-retardant mechanism found that ADP/BPs showed the fire-retardant impact of the condensed phase and gaseous phase. This work expands BPs in the flame-retardant application and could facilitate to prepare the anti-dripping flame-resistant TPEE.
Highlights
BPs as an efficient flame retardant were added into TPEE for the first time.
ADP/BPs as a synergistic combination has an excellent fire-retardant effect.
The introduction of BPs significantly reduced the addition of ADP.
TPEE/ADP-10/BPs-4 showed the highest FPI and the lowest FGI.
ADP/BPs has lowest negative effects on the mechanical performances of matrix.
期刊介绍:
Journal of Vinyl and Additive Technology is a peer-reviewed technical publication for new work in the fields of polymer modifiers and additives, vinyl polymers and selected review papers. Over half of all papers in JVAT are based on technology of additives and modifiers for all classes of polymers: thermoset polymers and both condensation and addition thermoplastics. Papers on vinyl technology include PVC additives.