N. G. Guliyeva, L. Yu. Jabbarova, I. I. Mustafayev, S. F. Aliyeva-Chichek
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Influence of Gamma Radiation on the Composition and Physicochemical Characteristics of Olefins: Post-Radiation Effects
The effect of gamma radiation on olefins was studied under static conditions at an absorbed dose of 65 kGy and at a dose rate of P = 0.076 Gy/s. The effect of radiation on the physicochemical characteristics and structural and group composition of the resulting olefins has been established. Post-radiation effects were studied immediately after irradiation and during 1, 2, 4, and 7 months later. When fuels are irradiated, polymerization of unsaturated hydrocarbons occurs. After the irradiation cessation, there occurs postpolymerization process. The chemical instability of olefins in fuels leads to the formation of carbon deposits in the engine system, tanks, and valves. IR spectra, iodine values, density, and kinematic viscosity of irradiated samples were measured.
期刊介绍:
Radiochemistry is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.