利用咔唑配体构建自旋交叉荧光双功能环链状 Fe(II) 化合物

IF 2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
Jing-Hui Zhou, Yu-Xiao Chen, Zhi-Kun Liu, Jie-Sheng Hu, Lu-Yao Wang, Yu-Meng Zhao, Ling-Tai Yue, Prof. Meng Yu, Prof. Jun Tao
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引用次数: 0

摘要

在自旋交叉(SCO)材料中加入荧光特性,旨在通过自旋态转变控制荧光,从而应用于磁光开关和信息处理,这是一个极具吸引力的研究方向。在本研究中,我们制备了两种一维环状链状铁(II)配位聚合物,分别命名为[Fe(DPPC)2(NCS)2]⋅CH3OH⋅o-C6H4Cl2(1、DPPC=3,6-二-4-吡啶基-9-[4-(4-吡啶基)苯基]-9H-咔唑)和[Fe(PDPC)2(NCS)2](2,PDPC=3,6-二(吡啶-4-基)-9-苯基-9H-咔唑)。通过单晶 X 射线研究和磁性测量分析,验证了 1 在 50~200 K 温度范围内的两步 SCO 行为。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Construction of Spin Crossover-Fluorescent Bifunctional Cyclic Chain-Like Fe(II) Compounds from Carbazole Ligands

Construction of Spin Crossover-Fluorescent Bifunctional Cyclic Chain-Like Fe(II) Compounds from Carbazole Ligands

Construction of Spin Crossover-Fluorescent Bifunctional Cyclic Chain-Like Fe(II) Compounds from Carbazole Ligands

The incorporation of fluorescent properties into spin-crossover (SCO) materials, aiming at controlling fluorescence via spin-state transitions for applications in magneto-optical switching and information processing, represents an appealing research direction. In this study, we prepared two examples of one-dimensional cyclic chain-like Fe(II) coordination polymers, denoted as [Fe(DPPC)2(NCS)2]⋅CH3OH⋅o-C6H4Cl2 (1, DPPC=3,6-di-4-pyridinyl-9-[4-(4-pyridinyl)phenyl]-9H-carbazole) and [Fe(PDPC)2(NCS)2] (2, PDPC=3,6-di(pyridin-4-yl)-9-phenyl-9H-carbazole). Analyses through single-crystal X-ray studies and magnetic measurements validate the two-step SCO behavior of 1 within the temperature range of 50~200 K. Additionally, when combined with temperature-dependent fluorescence emission spectroscopy, the results demonstrate the coexistence of SCO and fluorescence in 1.

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来源期刊
European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
4.30
自引率
4.30%
发文量
419
审稿时长
1.3 months
期刊介绍: The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
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