{"title":"用界面聚合法合成聚苯胺 (PANi),作为制造氨 (NH3) 气体传感器的基础材料","authors":"Neny Rasnyanti M Aras, Muhd. Irwan","doi":"10.36289/jtmi.v19i1.561","DOIUrl":null,"url":null,"abstract":"One of the main components in IoT-based devices is sensors. Polyaniline is a conductive polymer that has great potential to be developed as an active layer for chemical sensors because it has high sensitivity, is easy to synthesize and its electrical conductivity can be adjusted. This study aims to synthesize and characterize polyaniline using the interfacial polymerization method. In this study, polyaniline was synthesized by varying the aniline concentration of 2, 3, and 5 M, then its functional groups were characterized using FTIR and its conductivity and sensitivity were measured with an LCR meter. The result shows that polyaniline is in the form of emeraldine salt which is characterized by the formation of absorption bands at concentrations of 2, 3, and 5 M, respectively, 1,141.86 cm-1, 1,139 cm-1 and 1,139.93 cm-1. The highest conductivity was obtained at a concentration of 2 M, namely 4.9x10-5 and a sensitivity of 82.8% for an ammonia concentration of 100 ppm. So it can be concluded that the polyaniline obtained is a form of semiconducting emeraldine salt.","PeriodicalId":233858,"journal":{"name":"Jurnal Teknik Mesin Indonesia","volume":"55 6","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sintesis polianilin (PANi) dengan metode polimerisasi interfasial sebagai bahan dasar pembuatan sensor gas amonia (NH3)\",\"authors\":\"Neny Rasnyanti M Aras, Muhd. Irwan\",\"doi\":\"10.36289/jtmi.v19i1.561\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"One of the main components in IoT-based devices is sensors. Polyaniline is a conductive polymer that has great potential to be developed as an active layer for chemical sensors because it has high sensitivity, is easy to synthesize and its electrical conductivity can be adjusted. This study aims to synthesize and characterize polyaniline using the interfacial polymerization method. In this study, polyaniline was synthesized by varying the aniline concentration of 2, 3, and 5 M, then its functional groups were characterized using FTIR and its conductivity and sensitivity were measured with an LCR meter. The result shows that polyaniline is in the form of emeraldine salt which is characterized by the formation of absorption bands at concentrations of 2, 3, and 5 M, respectively, 1,141.86 cm-1, 1,139 cm-1 and 1,139.93 cm-1. The highest conductivity was obtained at a concentration of 2 M, namely 4.9x10-5 and a sensitivity of 82.8% for an ammonia concentration of 100 ppm. So it can be concluded that the polyaniline obtained is a form of semiconducting emeraldine salt.\",\"PeriodicalId\":233858,\"journal\":{\"name\":\"Jurnal Teknik Mesin Indonesia\",\"volume\":\"55 6\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Jurnal Teknik Mesin Indonesia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.36289/jtmi.v19i1.561\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Jurnal Teknik Mesin Indonesia","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.36289/jtmi.v19i1.561","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
传感器是物联网设备的主要组件之一。聚苯胺是一种导电聚合物,因其灵敏度高、易于合成且导电性能可调,被开发为化学传感器活性层的潜力巨大。本研究旨在利用界面聚合法合成聚苯胺并对其进行表征。本研究通过改变 2、3 和 5 M 苯胺浓度合成了聚苯胺,然后使用傅立叶变换红外光谱对其官能团进行了表征,并使用 LCR 仪测量了其电导率和灵敏度。结果表明,聚苯胺以祖母绿盐的形式存在,其特点是在浓度为 2、3 和 5 M 时形成吸收带,分别为 1,141.86 cm-1、1,139 cm-1 和 1,139.93 cm-1。浓度为 2 M 时的电导率最高,为 4.9x10-5,氨浓度为 100 ppm 时的灵敏度为 82.8%。因此可以得出结论,所获得的聚苯胺是一种半导体翡翠盐。
Sintesis polianilin (PANi) dengan metode polimerisasi interfasial sebagai bahan dasar pembuatan sensor gas amonia (NH3)
One of the main components in IoT-based devices is sensors. Polyaniline is a conductive polymer that has great potential to be developed as an active layer for chemical sensors because it has high sensitivity, is easy to synthesize and its electrical conductivity can be adjusted. This study aims to synthesize and characterize polyaniline using the interfacial polymerization method. In this study, polyaniline was synthesized by varying the aniline concentration of 2, 3, and 5 M, then its functional groups were characterized using FTIR and its conductivity and sensitivity were measured with an LCR meter. The result shows that polyaniline is in the form of emeraldine salt which is characterized by the formation of absorption bands at concentrations of 2, 3, and 5 M, respectively, 1,141.86 cm-1, 1,139 cm-1 and 1,139.93 cm-1. The highest conductivity was obtained at a concentration of 2 M, namely 4.9x10-5 and a sensitivity of 82.8% for an ammonia concentration of 100 ppm. So it can be concluded that the polyaniline obtained is a form of semiconducting emeraldine salt.