次磷酸钙-壳聚糖溶液复合硅溶胶提高棉织物的阻燃性能

Dan Cheng, Gang Li, Fei You
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引用次数: 0

摘要

为了提高棉织物的热稳定性和阻燃性,研究人员利用二氧化硅(SiO2)溶胶、次磷酸钙(CaHP)和壳聚糖(CS)制备了一种混合溶胶,然后通过浸渍-烘烤(干燥)法在棉织物表面进行整理。结果表明,CaHP-CS 和 SiO2 成功附着在棉织物表面。值得注意的是,CaHP-CS-SiO2@COT 的极限氧指数(LOI)值为 31.30 %(在所有样品中最高)。在锥形量热试验(CCT)中,研究发现 CaHP-CS-SiO2@COT 的峰值热释放率(PHPP)、火增长率(FGR)和 CO2/CO 值都是最低的。其阻燃性主要得益于 SiO2(提供具有尺寸结构的凝胶涂层,阻止氧气和热量的传播)、CaHP(促进棉纤维素脱水并形成芳香族炭)和 CS(稀释气态产物并冷却受热区域)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Enhancement of Flame Retardancy of Cotton Fabrics by Calcium Hypophosphite-Chitosan Solution Compound Silica Sol
To enhance the thermal stability and flame retardancy of cotton fabrics, a hybrid sol was prepared by using silica (SiO2) sol, calcium hypophosphite (CaHP) and chitosan (CS), then finished on the surface of cotton fabrics through dipping-baking (drying) method. The results show that the CaHP-CS and SiO2 are successfully attached to the cotton fabric surface. Remarkably, the limiting oxygen index (LOI) value of the CaHP-CS-SiO2@COT was 31.30 % ( the highest of all samples). In the cone calorimetry test (CCT), the study revealed that the CaHP-CS-SiO2@COT has the lowest peak heat release rate (PHPP), fire growth rate (FGR) and CO2/CO. Its flame retardancy is mainly enhanced by the SiO2 (provides a gel coating with dimensional structure to block the transmission of oxygen and heat, CaHP (promotes cotton cellulose to dehydrate and form aromatic chars) and CS (dilute gaseous products and cool down heated areas).
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