合成毛晶 V 的 A/D/E 环核心化合物。

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-04-23 DOI:10.1093/bbb/zbae049

Hiroki Asao, Yasuharu Shimasaki, Ayaka Sasaki, Shunki Katayama, K. Ida, Masaaki Kotake, Eriko Sato, Yuki Sato, Taiki Ishimoto, Minoru Izumi, C. Vavricka, Kuwahara Shigefumi, Hiromasa Kiyota

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引用次数: 0

摘要

实现了毛晶 V 的 A/D/E 环核心化合物的合成。三环α-亚甲基内酯与北原-丹尼舍夫斯基二烯之间的关键 Diels-Alder 反应以区域选择性和立体选择性的方式得到了螺环核心化合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Synthesis of the A/D/E-ring Core Compounds of Maoecrystal V.

Synthesis of the A/D/E-ring core compounds of maoecrystal V was achieved. The key Diels-Alder reactions between tricyclic α-methylene lactones and Kitahara-Danishefsky dienes afforded the spirocyclic core compounds in a regioselective and stereoselective manner.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.