D2O 和 H2O 二元溶液的密度、过量摩尔体积和过量折射率

IF 1.4 4区化学 Q4 CHEMISTRY, PHYSICAL

Journal of Solution Chemistry Pub Date : 2024-04-24 DOI:10.1007/s10953-024-01377-5

Shekhar Kumar

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引用次数: 0

摘要

重水是一种重要的工业化学品，用于利用天然铀进行核能发电，是核聚变发电所需的氚的前体，也是一种重要的化学和生物化学示踪剂。从天然或合成的 D2O-H2O 二元溶液中分离重水需要耗费大量能源。因此，要开发用于分离氚的化学和物理化学过程，D2O 和 H2O 二元溶液的物理特性非常重要。本研究报告了 D2O-H2O 二元溶液的密度、过量摩尔体积、折射率和相关性质。

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$Densities, Excess Molar Volumes and Excess Refractive Indices for Binary Solutions of D2O and H2O$

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Densities, Excess Molar Volumes and Excess Refractive Indices for Binary Solutions of D2O and H2O

Heavy water is an important industrial chemical for nuclear power generation from natural uranium, precursor for tritium, required for fusion power generation and an important chemical and biochemical tracer. Its separation from natural or synthetic D₂O–H₂O binary solutions is highly energy intensive. Therefore for development of chemical and physiochemical processes for its separation, physical properties of binary solutions of D₂O and H₂O are important. In this study, density, excess molar volume, refractive indices and related properties are reported for D₂O–H₂O binary solutions.

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来源期刊

Journal of Solution Chemistry 化学-物理化学

CiteScore

2.30

自引率

0.00%

发文量

审稿时长

3-8 weeks

期刊介绍： Journal of Solution Chemistry offers a forum for research on the physical chemistry of liquid solutions in such fields as physical chemistry, chemical physics, molecular biology, statistical mechanics, biochemistry, and biophysics. The emphasis is on papers in which the solvent plays a dominant rather than incidental role. Featured topics include experimental investigations of the dielectric, spectroscopic, thermodynamic, transport, or relaxation properties of both electrolytes and nonelectrolytes in liquid solutions.