Mei-Yi Liu, Jun Jiang, Hong-Tao Ji, Ke-Li Wang, Xiao-Jun Huang, Chao Wu, Wei-Min He
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H-bond promoted NPh3-mediated SrTiO3-photocatalyzed cascade decarboxylative coupling/annulation of benzo[d]isothiazole 1,1-dioxides
The first applying SrTiO3 semiconductor as a photocatalyst in organic synthesis and using NPh3 as a redox catalyst in photocatalysis was reported. With SrTiO3 as the heterogeneous photocatalyst, NPh3 as the homogeneous redox catalyst, H-bond as the promoter, paraformaldehyde as the cheap and atom economic methylene source, various 1,2,3,9b-tetrahydrobenzo[d]imidazo[1,5-b]isothiazole 5,5-dioxides can be efficiently synthesized through the visible-light-induced cascade decarboxylative coupling/annulation reaction.
期刊介绍:
The Journal of Catalysis publishes scholarly articles on both heterogeneous and homogeneous catalysis, covering a wide range of chemical transformations. These include various types of catalysis, such as those mediated by photons, plasmons, and electrons. The focus of the studies is to understand the relationship between catalytic function and the underlying chemical properties of surfaces and metal complexes.
The articles in the journal offer innovative concepts and explore the synthesis and kinetics of inorganic solids and homogeneous complexes. Furthermore, they discuss spectroscopic techniques for characterizing catalysts, investigate the interaction of probes and reacting species with catalysts, and employ theoretical methods.
The research presented in the journal should have direct relevance to the field of catalytic processes, addressing either fundamental aspects or applications of catalysis.