丁二烯酮:有机合成中一种尚未开发的中间体

IF 2 Q2 CHEMISTRY, ORGANIC
SynOpen Pub Date : 2024-04-22 DOI:10.1055/a-2302-3294
Maninderjeet K. Mann, Simranpreet K. Wahan, Nitin Tandon, Gaurav Bhargava
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引用次数: 0

摘要

丁二烯酮是一种有用的中间体,因为它在与多种底物(如简单或共轭亚胺和二烯)的环化反应中扮演着 2p 组份的角色。这篇综述文章总结了有关原位生成丁二烯基酮及其环加成反应生成杂环系统的最新报道。文章重点探讨了丁二烯基酮与各种亚胺和氮二烯衍生物(如 1,3-二氮杂茚-1,3-二烯)的 [2+2] 和 [4+2] 环化反应,分别用于合成四元和六元杂环。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Butadienyl Ketene: An Unexplored Intermediate in Organic Synthesis

Butadienyl Ketene: An Unexplored Intermediate in Organic Synthesis

Butadienyl ketene is a useful intermediate because of its role as a 2p-component in cycloaddition reactions with a variety of substrates such as simple or conjugated imines and dienes. This review article summarizes recent reports on the generation of butadienyl ketene in situ and their cycloaddition reactions to afford heterocyclic systems. The chemistry of butadienyl ketene is explored with a focus on its [2+2] and [4+2] cycloaddition reactions with a variety of imines and azadiene derivatives such as 1,3-diazabuta-1,3-dienes, for the synthesis of four- and six-membered heterocycles, respectively.

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来源期刊
SynOpen
SynOpen CHEMISTRY, ORGANIC-
CiteScore
2.30
自引率
4.00%
发文量
35
审稿时长
6 weeks
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