使用三醋酸纤维素光学薄膜的液晶显示器 (LCD) 光降解行为研究

IF 1.7 4区 工程技术 Q4 POLYMER SCIENCE
Xiushan Fan, Jin Wu
{"title":"使用三醋酸纤维素光学薄膜的液晶显示器 (LCD) 光降解行为研究","authors":"Xiushan Fan, Jin Wu","doi":"10.1515/polyeng-2023-0184","DOIUrl":null,"url":null,"abstract":"In this study, ramie fiber was employed to prepare cellulose triacetate (CTA) films. Subsequently, the photodegradation behaviors without photosensitizers of CTA films were carried out in photodegradation chambers at 40 °C. Additionally, the photodegradation procedure of films was assessed by the attenuated total reflection infrared (ATR-IR), <jats:sup>1</jats:sup>H nuclear magnetic resonance (<jats:sup>1</jats:sup>H NMR), scanning electron microscope (SEM), thermal properties, degree of substitution (DS), and tensile strength. The research consequences indicated that the mechanical strength of the CTA films was decreased significantly after ultraviolet (UV) irradiation for 300 h. However, the DS of the films is almost invariable when they are exposed to UV irradiation. Meanwhile, the suggested mechanism for photodegradation of CTA was also exhibited in this paper. This study provides a mild and potential pre-treatment approach for the biodegradation of LCD used waste CTA films.","PeriodicalId":16881,"journal":{"name":"Journal of Polymer Engineering","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2024-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on the photodegradation behaviors of liquid crystal display (LCD) used optical cellulose triacetate films\",\"authors\":\"Xiushan Fan, Jin Wu\",\"doi\":\"10.1515/polyeng-2023-0184\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this study, ramie fiber was employed to prepare cellulose triacetate (CTA) films. Subsequently, the photodegradation behaviors without photosensitizers of CTA films were carried out in photodegradation chambers at 40 °C. Additionally, the photodegradation procedure of films was assessed by the attenuated total reflection infrared (ATR-IR), <jats:sup>1</jats:sup>H nuclear magnetic resonance (<jats:sup>1</jats:sup>H NMR), scanning electron microscope (SEM), thermal properties, degree of substitution (DS), and tensile strength. The research consequences indicated that the mechanical strength of the CTA films was decreased significantly after ultraviolet (UV) irradiation for 300 h. However, the DS of the films is almost invariable when they are exposed to UV irradiation. Meanwhile, the suggested mechanism for photodegradation of CTA was also exhibited in this paper. This study provides a mild and potential pre-treatment approach for the biodegradation of LCD used waste CTA films.\",\"PeriodicalId\":16881,\"journal\":{\"name\":\"Journal of Polymer Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-04-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1515/polyeng-2023-0184\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Engineering","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1515/polyeng-2023-0184","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

摘要

本研究采用苎麻纤维制备三醋酸纤维素(CTA)薄膜。随后,在 40 °C 的光降解室中对不含光敏剂的 CTA 薄膜进行了光降解实验。此外,还通过衰减全反射红外线(ATR-IR)、1H 核磁共振(1H NMR)、扫描电子显微镜(SEM)、热性能、取代度(DS)和拉伸强度评估了薄膜的光降解过程。研究结果表明,紫外线(UV)辐照 300 小时后,CTA 薄膜的机械强度显著下降。同时,本文还展示了 CTA 光降解的机理。这项研究为液晶显示器废旧 CTA 薄膜的生物降解提供了一种温和且有潜力的预处理方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study on the photodegradation behaviors of liquid crystal display (LCD) used optical cellulose triacetate films
In this study, ramie fiber was employed to prepare cellulose triacetate (CTA) films. Subsequently, the photodegradation behaviors without photosensitizers of CTA films were carried out in photodegradation chambers at 40 °C. Additionally, the photodegradation procedure of films was assessed by the attenuated total reflection infrared (ATR-IR), 1H nuclear magnetic resonance (1H NMR), scanning electron microscope (SEM), thermal properties, degree of substitution (DS), and tensile strength. The research consequences indicated that the mechanical strength of the CTA films was decreased significantly after ultraviolet (UV) irradiation for 300 h. However, the DS of the films is almost invariable when they are exposed to UV irradiation. Meanwhile, the suggested mechanism for photodegradation of CTA was also exhibited in this paper. This study provides a mild and potential pre-treatment approach for the biodegradation of LCD used waste CTA films.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Polymer Engineering
Journal of Polymer Engineering 工程技术-高分子科学
CiteScore
3.20
自引率
5.00%
发文量
95
审稿时长
2.5 months
期刊介绍: Journal of Polymer Engineering publishes reviews, original basic and applied research contributions as well as recent technological developments in polymer engineering. Polymer engineering is a strongly interdisciplinary field and papers published by the journal may span areas such as polymer physics, polymer processing and engineering of polymer-based materials and their applications. The editors and the publisher are committed to high quality standards and rapid handling of the peer review and publication processes.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信