Electropolishing of gold and gold alloys in HCl-glycerol-ethanol electrolytes

Electropolishing or electrochemical polishing (EP) is an ultrafinishing process that improves esthetic, technical and functional properties of metallic surfaces by reducing their roughness. This process is based on anodic dissolution of the workpiece through an oxidation reaction. For many years, cyanide-based electrolytes were used to electropolish precious metals like gold and its alloys. The need for safer working conditions encouraged the replacement of cyanide by other complexing agents, mainly thiourea. However, the latter is also harmful. Therefore, the aim of this work is to electropolish pure gold and 18k jewelry gold alloys (yellow, rose, red and gray) in a cyanide-free electrolyte, to evaluate the electrochemical behavior and the influence of different parameters. For this purpose, a previously reported solution based on hydrochloric acid and glycerol was used. In the first part of the study, the influence of chloride concentration on pure gold EP was determined by electrochemical techniques and surface properties analysis. The effects of adding ethanol to electrolyte composition and of variating rotation speed were also evaluated. The best results were obtained for a HCl 50% vol. - Glycerol 25 % vol. - Ethanol 25 % vol. electrolyte at a rotation speed of 1000 rpm. In the second part of the study, this solution was used to electropolish 18 K gold alloys. Silver-containing alloys were not uniformly polished due to the formation of an AgCl film on the surface that partially masks the substrates.