制备高多孔片状 Fe3O4 碳纳米复合材料:电催化氧进化反应的多功能催化剂

IF 2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Prof. S. A. T. Shanmugapriya, Anand Kumar, Mohd Afzal, Ratiram Gomaji Chaudhary, Kotesh Kumar Mandari, Aniruddha Mondal, Sudip Mondal
{"title":"制备高多孔片状 Fe3O4 碳纳米复合材料:电催化氧进化反应的多功能催化剂","authors":"Prof. S. A. T. Shanmugapriya,&nbsp;Anand Kumar,&nbsp;Mohd Afzal,&nbsp;Ratiram Gomaji Chaudhary,&nbsp;Kotesh Kumar Mandari,&nbsp;Aniruddha Mondal,&nbsp;Sudip Mondal","doi":"10.1002/slct.202304092","DOIUrl":null,"url":null,"abstract":"<p>Fuel cells and metal-air batteries are examples of renewable energy technologies that depend on having highly effective electrocatalysts for the oxygen evolution reaction (OER). In this study, a mesoporous nanostructure composed of Fe<sub>3</sub>O<sub>4</sub>-Carbon nanocomposites was synthesised using a simple and economically viable approach at a relatively low temperature. The observed catalytic activity of the prepared defected Fe<sub>3</sub>O<sub>4</sub>-Carbon nanocomposites mesoporous nanostructure was found to be remarkable. Additionally, the nanostructure exhibited a high tolerance to methanol and demonstrated durability towards the oxygen evolution reaction (OER) in alkaline media. In the course of the experiment, it was observed that the catalyst exhibited noteworthy activity in the Oxygen Evolution Reaction (OER) when compared to the commercially available RuO<sub>2</sub> catalyst. This was evident through a more overpotential value of 325 mV at current density of 10 mA/cm<sup>2</sup>. The catalyst‘s notable capacity for high oxygen reaction activity may potentially enhance the synergistic effect resulting from the combination of defect sites and the porous structure of Fe<sub>3</sub>O<sub>4</sub>-Carbon nanocomposites. The findings of this study indicate that the Fe<sub>3</sub>O<sub>4</sub>-Carbon nanocomposites nanostructures exhibit promising attributes as an electrocatalyst for the oxygen evolution reaction (OER) in real-world scenarios.</p>","PeriodicalId":146,"journal":{"name":"ChemistrySelect","volume":"9 15","pages":""},"PeriodicalIF":2.0000,"publicationDate":"2024-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fabrication of Highly Porous and Sheet Like Fe3O4-Carbon Nanocomposites: A Versatile Catalyst for Electrocatalytic Oxygen Evolution Reactions\",\"authors\":\"Prof. S. A. T. Shanmugapriya,&nbsp;Anand Kumar,&nbsp;Mohd Afzal,&nbsp;Ratiram Gomaji Chaudhary,&nbsp;Kotesh Kumar Mandari,&nbsp;Aniruddha Mondal,&nbsp;Sudip Mondal\",\"doi\":\"10.1002/slct.202304092\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Fuel cells and metal-air batteries are examples of renewable energy technologies that depend on having highly effective electrocatalysts for the oxygen evolution reaction (OER). In this study, a mesoporous nanostructure composed of Fe<sub>3</sub>O<sub>4</sub>-Carbon nanocomposites was synthesised using a simple and economically viable approach at a relatively low temperature. The observed catalytic activity of the prepared defected Fe<sub>3</sub>O<sub>4</sub>-Carbon nanocomposites mesoporous nanostructure was found to be remarkable. Additionally, the nanostructure exhibited a high tolerance to methanol and demonstrated durability towards the oxygen evolution reaction (OER) in alkaline media. In the course of the experiment, it was observed that the catalyst exhibited noteworthy activity in the Oxygen Evolution Reaction (OER) when compared to the commercially available RuO<sub>2</sub> catalyst. This was evident through a more overpotential value of 325 mV at current density of 10 mA/cm<sup>2</sup>. The catalyst‘s notable capacity for high oxygen reaction activity may potentially enhance the synergistic effect resulting from the combination of defect sites and the porous structure of Fe<sub>3</sub>O<sub>4</sub>-Carbon nanocomposites. The findings of this study indicate that the Fe<sub>3</sub>O<sub>4</sub>-Carbon nanocomposites nanostructures exhibit promising attributes as an electrocatalyst for the oxygen evolution reaction (OER) in real-world scenarios.</p>\",\"PeriodicalId\":146,\"journal\":{\"name\":\"ChemistrySelect\",\"volume\":\"9 15\",\"pages\":\"\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2024-04-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemistrySelect\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/slct.202304092\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemistrySelect","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/slct.202304092","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

燃料电池和金属-空气电池是可再生能源技术的典范,它们依赖于高效的氧进化反应(OER)电催化剂。在本研究中,采用一种简单而经济可行的方法,在相对较低的温度下合成了一种由 Fe3O4-Carbon 纳米复合材料组成的介孔纳米结构。研究发现,制备的缺损 Fe3O4 碳纳米复合材料介孔纳米结构具有显著的催化活性。此外,该纳米结构对甲醇具有很高的耐受性,并在碱性介质中对氧进化反应(OER)表现出耐久性。在实验过程中观察到,与市售的 RuO2 催化剂相比,该催化剂在氧进化反应(OER)中表现出显著的活性。在电流密度为 10 mA/cm2 时,过电位值为 325 mV。该催化剂显著的高氧反应活性可能会增强缺陷位点与 Fe3O4-Carbon 纳米复合材料多孔结构相结合所产生的协同效应。本研究的结果表明,Fe3O4-碳纳米复合材料纳米结构在实际应用中作为氧进化反应(OER)的电催化剂具有良好的前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Fabrication of Highly Porous and Sheet Like Fe3O4-Carbon Nanocomposites: A Versatile Catalyst for Electrocatalytic Oxygen Evolution Reactions

Fabrication of Highly Porous and Sheet Like Fe3O4-Carbon Nanocomposites: A Versatile Catalyst for Electrocatalytic Oxygen Evolution Reactions

Fuel cells and metal-air batteries are examples of renewable energy technologies that depend on having highly effective electrocatalysts for the oxygen evolution reaction (OER). In this study, a mesoporous nanostructure composed of Fe3O4-Carbon nanocomposites was synthesised using a simple and economically viable approach at a relatively low temperature. The observed catalytic activity of the prepared defected Fe3O4-Carbon nanocomposites mesoporous nanostructure was found to be remarkable. Additionally, the nanostructure exhibited a high tolerance to methanol and demonstrated durability towards the oxygen evolution reaction (OER) in alkaline media. In the course of the experiment, it was observed that the catalyst exhibited noteworthy activity in the Oxygen Evolution Reaction (OER) when compared to the commercially available RuO2 catalyst. This was evident through a more overpotential value of 325 mV at current density of 10 mA/cm2. The catalyst‘s notable capacity for high oxygen reaction activity may potentially enhance the synergistic effect resulting from the combination of defect sites and the porous structure of Fe3O4-Carbon nanocomposites. The findings of this study indicate that the Fe3O4-Carbon nanocomposites nanostructures exhibit promising attributes as an electrocatalyst for the oxygen evolution reaction (OER) in real-world scenarios.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
ChemistrySelect
ChemistrySelect Chemistry-General Chemistry
CiteScore
3.30
自引率
4.80%
发文量
1809
审稿时长
1.6 months
期刊介绍: ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信