Highly efficient three-dimensional solar evaporator for zero liquid discharge desalination of high-salinity brine

Solar-driven interfacial evaporation is a promising technology for freshwater production from seawater, but salt accumulation on the evaporator surface hinders its performance and sustainability. In this study, we report a simple and green strategy to fabricate a three-dimensional porous graphene spiral roll (3GSR) that enables highly efficient solar evaporation, salt collection, and water production from near-saturated brine with zero liquid discharge (ZLD). The 3GSR design facilitates energy recovery, radial brine transport, and directional salt crystallization, thereby resulting in an ultrahigh evaporation rate of 9.05 kg m⁻² h⁻¹ in 25 wt% brine under 1-sun illumination for 48 h continuously. Remarkably, the directional salt crystallization on its outer surface not only enlarges the evaporation area but also achieves an ultrahigh salt collection rate of 2.92 kg m⁻² h⁻¹, thus enabling ZLD desalination. Additionally,  3GSR exhibits a record-high water production rate of 3.14 kg m⁻² h⁻¹ in an outdoor test. This innovative solution offers a highly efficient and continuous solar desalination method for water production and ZLD brine treatment, which has great implications for addressing global water scarcity and environmental issues arising from brine disposal.