Zhiru Yang, Jinxing Li, Jiaoyi Wu, Hai Zhou, Wentao Hou
{"title":"利用激光诱导自制前驱体制作柔性氮掺杂石墨烯微型超级电容器","authors":"Zhiru Yang, Jinxing Li, Jiaoyi Wu, Hai Zhou, Wentao Hou","doi":"10.1007/s42823-024-00725-1","DOIUrl":null,"url":null,"abstract":"<div><p>With the wide application of portable wearable devices, a variety of electronic energy storage devices, including micro-supercapacitors (MSCs), have attracted wide attention. Laser-induced graphene (LIG) is widely used as electrode material for MSCs because of its large porosity and specific surface area. To further improve the performance of MSCs, it is an effective way to increase the specific surface area and the number of internal active sites of laser-induced graphene electrode materials. In this paper, N-doped polyimide/polyvinyl alcohol (PVA) as precursor was used to achieve in situ doping of nitrogen atoms in laser-induced graphene by laser irradiation. Through the addition of N atoms, nitrogen-doped laser-induced three-dimensional porous graphene (N-LIG) exhibits large specific surface area, many active sites, and good wettability all of which are favorable conditions for enhancing the capacitive properties of laser-induced graphene. After assembly with PVA/H<sub>2</sub>SO<sub>4</sub> as gel electrolyte, the high surface capacitance of the MSC device with N-LIG as electrode material is 16.57 mF cm<sup>−2</sup> at the scanning rate of 5 mV s<sup>−1</sup>, which is much higher than the 2.89 mF cm<sup>−2</sup> of the MSC device with LIG as electrode material. In addition, MSC devices with N-LIG as electrode materials have shown excellent cyclic stability and flexibility in practical tests, so they have a high application prospect in the field of flexible wearable microelectronics.</p></div>","PeriodicalId":506,"journal":{"name":"Carbon Letters","volume":"34 6","pages":"1707 - 1721"},"PeriodicalIF":5.5000,"publicationDate":"2024-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fabrication of flexible nitrogen-doped graphene micro-supercapacitors by laser-induced self-made precursors\",\"authors\":\"Zhiru Yang, Jinxing Li, Jiaoyi Wu, Hai Zhou, Wentao Hou\",\"doi\":\"10.1007/s42823-024-00725-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>With the wide application of portable wearable devices, a variety of electronic energy storage devices, including micro-supercapacitors (MSCs), have attracted wide attention. Laser-induced graphene (LIG) is widely used as electrode material for MSCs because of its large porosity and specific surface area. To further improve the performance of MSCs, it is an effective way to increase the specific surface area and the number of internal active sites of laser-induced graphene electrode materials. In this paper, N-doped polyimide/polyvinyl alcohol (PVA) as precursor was used to achieve in situ doping of nitrogen atoms in laser-induced graphene by laser irradiation. Through the addition of N atoms, nitrogen-doped laser-induced three-dimensional porous graphene (N-LIG) exhibits large specific surface area, many active sites, and good wettability all of which are favorable conditions for enhancing the capacitive properties of laser-induced graphene. After assembly with PVA/H<sub>2</sub>SO<sub>4</sub> as gel electrolyte, the high surface capacitance of the MSC device with N-LIG as electrode material is 16.57 mF cm<sup>−2</sup> at the scanning rate of 5 mV s<sup>−1</sup>, which is much higher than the 2.89 mF cm<sup>−2</sup> of the MSC device with LIG as electrode material. In addition, MSC devices with N-LIG as electrode materials have shown excellent cyclic stability and flexibility in practical tests, so they have a high application prospect in the field of flexible wearable microelectronics.</p></div>\",\"PeriodicalId\":506,\"journal\":{\"name\":\"Carbon Letters\",\"volume\":\"34 6\",\"pages\":\"1707 - 1721\"},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2024-04-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Carbon Letters\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s42823-024-00725-1\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon Letters","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s42823-024-00725-1","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Fabrication of flexible nitrogen-doped graphene micro-supercapacitors by laser-induced self-made precursors
With the wide application of portable wearable devices, a variety of electronic energy storage devices, including micro-supercapacitors (MSCs), have attracted wide attention. Laser-induced graphene (LIG) is widely used as electrode material for MSCs because of its large porosity and specific surface area. To further improve the performance of MSCs, it is an effective way to increase the specific surface area and the number of internal active sites of laser-induced graphene electrode materials. In this paper, N-doped polyimide/polyvinyl alcohol (PVA) as precursor was used to achieve in situ doping of nitrogen atoms in laser-induced graphene by laser irradiation. Through the addition of N atoms, nitrogen-doped laser-induced three-dimensional porous graphene (N-LIG) exhibits large specific surface area, many active sites, and good wettability all of which are favorable conditions for enhancing the capacitive properties of laser-induced graphene. After assembly with PVA/H2SO4 as gel electrolyte, the high surface capacitance of the MSC device with N-LIG as electrode material is 16.57 mF cm−2 at the scanning rate of 5 mV s−1, which is much higher than the 2.89 mF cm−2 of the MSC device with LIG as electrode material. In addition, MSC devices with N-LIG as electrode materials have shown excellent cyclic stability and flexibility in practical tests, so they have a high application prospect in the field of flexible wearable microelectronics.
期刊介绍:
Carbon Letters aims to be a comprehensive journal with complete coverage of carbon materials and carbon-rich molecules. These materials range from, but are not limited to, diamond and graphite through chars, semicokes, mesophase substances, carbon fibers, carbon nanotubes, graphenes, carbon blacks, activated carbons, pyrolytic carbons, glass-like carbons, etc. Papers on the secondary production of new carbon and composite materials from the above mentioned various carbons are within the scope of the journal. Papers on organic substances, including coals, will be considered only if the research has close relation to the resulting carbon materials. Carbon Letters also seeks to keep abreast of new developments in their specialist fields and to unite in finding alternative energy solutions to current issues such as the greenhouse effect and the depletion of the ozone layer. The renewable energy basics, energy storage and conversion, solar energy, wind energy, water energy, nuclear energy, biomass energy, hydrogen production technology, and other clean energy technologies are also within the scope of the journal. Carbon Letters invites original reports of fundamental research in all branches of the theory and practice of carbon science and technology.