Xinyu Cao, Yangpeng Zhang, Lijian Rong, Desheng Yan
{"title":"锰对耐热钢表面预氧化膜生长行为的影响","authors":"Xinyu Cao, Yangpeng Zhang, Lijian Rong, Desheng Yan","doi":"10.1007/s11085-024-10242-1","DOIUrl":null,"url":null,"abstract":"<div><p>The phase composition of the pre-oxidized film on an alloy surface usually has a great influence on its corrosion resistance. In this work, the surface oxide film growth behavior in low-oxygen atmosphere at 720 °C of two 12Cr heat-resistant steels with different Mn content was studied, and their corrosion resistance in liquid lead–bismuth eutectic (LBE) with saturated oxygen at 600 °C was tested. The results indicated that the pre-oxidized film of 1.6Mn steel is mainly composed of large-size Mn–Cr spinel and Fe–Cr spinel, while that of improved 0Mn steel is mainly composed of continuous and dense Cr<sub>2</sub>O<sub>3</sub> and Fe–Cr spinel. This is because Mn has a high diffusion rate in Cr<sub>2</sub>O<sub>3</sub>, so it can pass through the Cr<sub>2</sub>O<sub>3</sub> layer and combine with O to form Mn-rich oxides, and then the Mn-rich oxides react with Cr<sub>2</sub>O<sub>3</sub> to form Mn–Cr spinel. However, due to the high solubility of Mn in LBE, the Mn-rich pre-oxidized film of 1.6Mn steel will dissolve and fail quickly, so its long-term corrosion resistance in LBE is lower than that of 0Mn steel.</p></div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"101 4","pages":"729 - 754"},"PeriodicalIF":2.1000,"publicationDate":"2024-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Mn on the Growth Behavior of Pre-oxidized Film on the Heat-resistant Steel Surface\",\"authors\":\"Xinyu Cao, Yangpeng Zhang, Lijian Rong, Desheng Yan\",\"doi\":\"10.1007/s11085-024-10242-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The phase composition of the pre-oxidized film on an alloy surface usually has a great influence on its corrosion resistance. In this work, the surface oxide film growth behavior in low-oxygen atmosphere at 720 °C of two 12Cr heat-resistant steels with different Mn content was studied, and their corrosion resistance in liquid lead–bismuth eutectic (LBE) with saturated oxygen at 600 °C was tested. The results indicated that the pre-oxidized film of 1.6Mn steel is mainly composed of large-size Mn–Cr spinel and Fe–Cr spinel, while that of improved 0Mn steel is mainly composed of continuous and dense Cr<sub>2</sub>O<sub>3</sub> and Fe–Cr spinel. This is because Mn has a high diffusion rate in Cr<sub>2</sub>O<sub>3</sub>, so it can pass through the Cr<sub>2</sub>O<sub>3</sub> layer and combine with O to form Mn-rich oxides, and then the Mn-rich oxides react with Cr<sub>2</sub>O<sub>3</sub> to form Mn–Cr spinel. However, due to the high solubility of Mn in LBE, the Mn-rich pre-oxidized film of 1.6Mn steel will dissolve and fail quickly, so its long-term corrosion resistance in LBE is lower than that of 0Mn steel.</p></div>\",\"PeriodicalId\":724,\"journal\":{\"name\":\"Oxidation of Metals\",\"volume\":\"101 4\",\"pages\":\"729 - 754\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-04-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Oxidation of Metals\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11085-024-10242-1\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Oxidation of Metals","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11085-024-10242-1","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Effect of Mn on the Growth Behavior of Pre-oxidized Film on the Heat-resistant Steel Surface
The phase composition of the pre-oxidized film on an alloy surface usually has a great influence on its corrosion resistance. In this work, the surface oxide film growth behavior in low-oxygen atmosphere at 720 °C of two 12Cr heat-resistant steels with different Mn content was studied, and their corrosion resistance in liquid lead–bismuth eutectic (LBE) with saturated oxygen at 600 °C was tested. The results indicated that the pre-oxidized film of 1.6Mn steel is mainly composed of large-size Mn–Cr spinel and Fe–Cr spinel, while that of improved 0Mn steel is mainly composed of continuous and dense Cr2O3 and Fe–Cr spinel. This is because Mn has a high diffusion rate in Cr2O3, so it can pass through the Cr2O3 layer and combine with O to form Mn-rich oxides, and then the Mn-rich oxides react with Cr2O3 to form Mn–Cr spinel. However, due to the high solubility of Mn in LBE, the Mn-rich pre-oxidized film of 1.6Mn steel will dissolve and fail quickly, so its long-term corrosion resistance in LBE is lower than that of 0Mn steel.
期刊介绍：
Oxidation of Metals is the premier source for the rapid dissemination of current research on all aspects of the science of gas-solid reactions at temperatures greater than about 400˚C, with primary focus on the high-temperature corrosion of bulk and coated systems. This authoritative bi-monthly publishes original scientific papers on kinetics, mechanisms, studies of scales from structural and morphological viewpoints, transport properties in scales, phase-boundary reactions, and much more. Articles may discuss both theoretical and experimental work related to gas-solid reactions at the surface or near-surface of a material exposed to elevated temperatures, including reactions with oxygen, nitrogen, sulfur, carbon and halogens. In addition, Oxidation of Metals publishes the results of frontier research concerned with deposit-induced attack. Review papers and short technical notes are encouraged.
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