钙铝铼钠盐石，钠盐石笼中含有可还原的铼

IF 1.8 4区材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY

MRS Communications Pub Date : 2024-04-12 DOI:10.1557/s43579-024-00550-7

Danrui Ni, Guangming Cheng, Lun Jin, Chen Yang, Nan Yao, Robert J. Cava

{"title":"钙铝铼钠盐石，钠盐石笼中含有可还原的铼","authors":"Danrui Ni, Guangming Cheng, Lun Jin, Chen Yang, Nan Yao, Robert J. Cava","doi":"10.1557/s43579-024-00550-7","DOIUrl":null,"url":null,"abstract":"<p>An unreported rhenium-based calcium aluminum sodalite (CARe sodalite) has been synthesized by a traditional solid-state method. The rhenium is located in the sodalite β-cage and can be reduced under 5% H<sub>2</sub> forming gas without breaking the cage framework. Preliminary characterizations of the structural, optical, and magnetic properties are reported.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>\n","PeriodicalId":19016,"journal":{"name":"MRS Communications","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A calcium aluminum rhenium sodalite with reducible rhenium in the sodalite cage\",\"authors\":\"Danrui Ni, Guangming Cheng, Lun Jin, Chen Yang, Nan Yao, Robert J. Cava\",\"doi\":\"10.1557/s43579-024-00550-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>An unreported rhenium-based calcium aluminum sodalite (CARe sodalite) has been synthesized by a traditional solid-state method. The rhenium is located in the sodalite β-cage and can be reduced under 5% H<sub>2</sub> forming gas without breaking the cage framework. Preliminary characterizations of the structural, optical, and magnetic properties are reported.</p><h3 data-test=\\\"abstract-sub-heading\\\">Graphical abstract</h3>\\n\",\"PeriodicalId\":19016,\"journal\":{\"name\":\"MRS Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-04-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"MRS Communications\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1557/s43579-024-00550-7\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"MRS Communications","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1557/s43579-024-00550-7","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

通过传统的固态方法合成了一种未报道过的铼基钙铝钠盐石（CARe sodalite）。铼位于钠铝石的 β 笼中，可在 5% 的 H2 生成气体中还原而不破坏笼的框架。报告对其结构、光学和磁学特性进行了初步表征。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A calcium aluminum rhenium sodalite with reducible rhenium in the sodalite cage

查看原文本刊更多论文

A calcium aluminum rhenium sodalite with reducible rhenium in the sodalite cage

An unreported rhenium-based calcium aluminum sodalite (CARe sodalite) has been synthesized by a traditional solid-state method. The rhenium is located in the sodalite β-cage and can be reduced under 5% H₂ forming gas without breaking the cage framework. Preliminary characterizations of the structural, optical, and magnetic properties are reported.

Graphical abstract

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

MRS Communications MATERIALS SCIENCE, MULTIDISCIPLINARY-

CiteScore

2.60

自引率

10.50%

发文量

166

审稿时长

>12 weeks

期刊介绍： MRS Communications is a full-color, high-impact journal focused on rapid publication of completed research with broad appeal to the materials community. MRS Communications offers a rapid but rigorous peer-review process and time to publication. Leveraging its access to the far-reaching technical expertise of MRS members and leading materials researchers from around the world, the journal boasts an experienced and highly respected board of principal editors and reviewers.