利用 AMP-PAN 树脂和样品装载设备快速浓缩海水中铯的方法

IF 1.6 3区化学 Q3 CHEMISTRY, ANALYTICAL

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2024-04-01 DOI:10.1007/s10967-024-09465-y

Gahyun Kim, Jong-Myoung Lim, Hyuncheol Kim

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引用次数: 0

摘要

摘要我们在此介绍一种使用钼磷酸铵-聚丙烯腈（AMP-PAN）树脂浓缩海水中铯的方法，该方法使用定制的样品装载设备。该设备由八台蠕动泵与八根柱子并联而成，每根柱子都装有 AMP-PAN，旨在减少分析时间和人力。使用该方法在 6 小时内将 80 升含铯海水浓缩至 0.01 升，铯的回收率为 85%。使用高纯度锗探测器进行 160,000 秒测量时，可检测到的最小放射性活度为 0.2 mBq L-1。

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Rapid concentration method for radiocesium in seawater using AMP-PAN resin and sample loading equipment

Here, we present a method for concentrating radiocesium in seawater using ammonium molybdophosphate-polyacrylonitrile (AMP-PAN) resin using custom-made sample-loading equipment. It was designed to reduce analytical time and labor with eight peristaltic pumps connected in parallel with eight columns, each packed with AMP-PAN. Eighty liters of seawater containing radiocesium were concentrated to 0.01 L in 6 h with the proposed method and Cs recovery was > 85%. The minimum detectable activity was 0.2 mBq L^–1 at 160,000-s measurement with a high-purity germanium detector.

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来源期刊

Journal of Radioanalytical and Nuclear Chemistry 化学-分析化学

CiteScore

2.80

自引率

18.80%

发文量

504

审稿时长

2.2 months

期刊介绍： An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.