{"title":"双向性对分子催化动力学建模的影响","authors":"Andrea Fasano, Vincent Fourmond, Christophe Léger","doi":"10.1016/j.coelec.2024.101489","DOIUrl":null,"url":null,"abstract":"<div><p>The quantitative modeling of voltammograms obtained with molecular redox catalysts is important for mechanistic studies and benchmarking. Most kinetic models developed for that purpose were based on unidirectional reaction mechanisms, but many redox enzymes work in both directions of the reaction, and chemists have recently successfully designed bidirectional, synthetic, molecular catalysts. An important conclusion from recent work is that unidirectional kinetic models should not be used to interpret bidirectional electrochemical responses. Understanding the latter will require much more work than simply adapting unidirectional models.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":null,"pages":null},"PeriodicalIF":7.9000,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2451910324000504/pdfft?md5=9049964f495d08d054a7e7fbe866aad9&pid=1-s2.0-S2451910324000504-main.pdf","citationCount":"0","resultStr":"{\"title\":\"The difference bidirectionality makes to the kinetic modeling of molecular catalysis\",\"authors\":\"Andrea Fasano, Vincent Fourmond, Christophe Léger\",\"doi\":\"10.1016/j.coelec.2024.101489\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The quantitative modeling of voltammograms obtained with molecular redox catalysts is important for mechanistic studies and benchmarking. Most kinetic models developed for that purpose were based on unidirectional reaction mechanisms, but many redox enzymes work in both directions of the reaction, and chemists have recently successfully designed bidirectional, synthetic, molecular catalysts. An important conclusion from recent work is that unidirectional kinetic models should not be used to interpret bidirectional electrochemical responses. Understanding the latter will require much more work than simply adapting unidirectional models.</p></div>\",\"PeriodicalId\":11028,\"journal\":{\"name\":\"Current Opinion in Electrochemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":7.9000,\"publicationDate\":\"2024-03-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2451910324000504/pdfft?md5=9049964f495d08d054a7e7fbe866aad9&pid=1-s2.0-S2451910324000504-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Current Opinion in Electrochemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2451910324000504\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Opinion in Electrochemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2451910324000504","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
The difference bidirectionality makes to the kinetic modeling of molecular catalysis
The quantitative modeling of voltammograms obtained with molecular redox catalysts is important for mechanistic studies and benchmarking. Most kinetic models developed for that purpose were based on unidirectional reaction mechanisms, but many redox enzymes work in both directions of the reaction, and chemists have recently successfully designed bidirectional, synthetic, molecular catalysts. An important conclusion from recent work is that unidirectional kinetic models should not be used to interpret bidirectional electrochemical responses. Understanding the latter will require much more work than simply adapting unidirectional models.
期刊介绍:
The development of the Current Opinion journals stemmed from the acknowledgment of the growing challenge for specialists to stay abreast of the expanding volume of information within their field. In Current Opinion in Electrochemistry, they help the reader by providing in a systematic manner:
1.The views of experts on current advances in electrochemistry in a clear and readable form.
2.Evaluations of the most interesting papers, annotated by experts, from the great wealth of original publications.
In the realm of electrochemistry, the subject is divided into 12 themed sections, with each section undergoing an annual review cycle:
• Bioelectrochemistry • Electrocatalysis • Electrochemical Materials and Engineering • Energy Storage: Batteries and Supercapacitors • Energy Transformation • Environmental Electrochemistry • Fundamental & Theoretical Electrochemistry • Innovative Methods in Electrochemistry • Organic & Molecular Electrochemistry • Physical & Nano-Electrochemistry • Sensors & Bio-sensors •