Byung-Moon Jun , Seong-Nam Nam , Bongyeon Jung , Jong Soo Choi , Chang Min Park , Choe Earn Choong , Min Jang , Eun Hea Jho , Ahjeong Son , Yeomin Yoon
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引用次数: 0
摘要
双酚 A(BPA)是一种公认的干扰内分泌的化合物,已在饮用水源/成品水和生活废水进水/出水中被发现。大量研究表明,光催化和电催化氧化对去除双酚 A 非常有效,特别是在添加石墨烯/氧化石墨烯(GO)基纳米催化剂的情况下。然而,关于双酚 A 在水溶液中的光催化和电催化降解还没有进行过综述。因此,本综述将全面介绍在石墨烯/GO 基纳米催化剂存在下,双酚 A 在光催化/电催化活性过程中的降解情况。在此,本综述评估了在各种水质/化学条件(pH 值、背景离子、天然有机物、促进剂和清除剂)、各种石墨烯/GO 基纳米催化剂的理化特性以及各种操作条件(电压和电流)下,去除双酚 A 的主要光催化/电催化降解机制和途径。此外,还简要介绍了石墨烯/GO 基纳米催化剂的可重复使用性/稳定性、与臭氧/超声波/芬顿氧化相结合的混合系统以及前瞻性研究领域。
Photocatalytic and electrocatalytic degradation of bisphenol A in the presence of graphene/graphene oxide-based nanocatalysts: A review
Bisphenol A (BPA), a widely recognized endocrine disrupting compound, has been discovered in drinking water sources/finished water and domestic wastewater influent/effluent. Numerous studies have shown photocatalytic and electrocatalytic oxidation to be very effective for the removal of BPA, particularly in the addition of graphene/graphene oxide (GO)-based nanocatalysts. Nevertheless, the photocatalytic and electrocatalytic degradation of BPA in aqueous solutions has not been reviewed. Therefore, this review gives a comprehensive understanding of BPA degradation during photo-/electro-catalytic activity in the presence of graphene/GO-based nanocatalysts. Herein, this review evaluated the main photo-/electro-catalytic degradation mechanisms and pathways for BPA removal under various water quality/chemistry conditions (pH, background ions, natural organic matter, promotors, and scavengers), the physicochemical characteristics of various graphene/GO-based nanocatalysts, and various operating conditions (voltage and current). Additionally, the reusability/stability of graphene/GO-based nanocatalysts, hybrid systems combined with ozone/ultrasonic/Fenton oxidation, and prospective research areas are briefly described.
期刊介绍:
Chemosphere, being an international multidisciplinary journal, is dedicated to publishing original communications and review articles on chemicals in the environment. The scope covers a wide range of topics, including the identification, quantification, behavior, fate, toxicology, treatment, and remediation of chemicals in the bio-, hydro-, litho-, and atmosphere, ensuring the broad dissemination of research in this field.