Magdalena Sobczak , Sebastian Bujnowicz , Lucyna Bilińska
{"title":"用于工业纺织废水回收的 Fenton 和电 Fenton 处理。副产品去除率、生物降解性、毒性和再染色的比较","authors":"Magdalena Sobczak , Sebastian Bujnowicz , Lucyna Bilińska","doi":"10.1016/j.wri.2024.100256","DOIUrl":null,"url":null,"abstract":"<div><p>A comparative study of the results obtained from using Fenton and electro-Fenton processes in textile wastewater treatment is presented. Global indicators, color, COD, TOC, and BOD<sub>5</sub> were employed to investigate the treatments. Examination of the representative by-products gave new insights into Fenton. Even though the color removal was higher for classical Fenton (almost 100% color removal) than for electro-Fenton, the overall purification effect was not directly advantageous for Fenton. We found that electro-Fenton removed COD and TOC more efficiently. The biodegradability BI (BOD<sub>5</sub>/COD) parameter was investigated, where the textile wastewater was hardly biodegradable (BI was 0.12 ± 0.007). BI of Fenton was also low (0.044 ± 0.006). Electro-Fenton yielded a considerably more promising result, where BI was 0.83 ± 0.15, and proved more bio-friendly than classical Fenton. Additionally, electro-Fenton was more efficient in by-product removal, especially the naphthalic component, with 90% removal (while Fenton removed 50%). The by-products influenced the after-treatment toxicity assessment of <em>V. fischeri.</em> The EC<sub>50</sub> values were below 2% and even lower for electro-Fenton. The results of the color matching parameters (DE<sub>CMC</sub>) of re-dyeing were unacceptable using after-Fenton water at 8.66. DE<sub>CMC</sub> results were between 1.01 and 2.71 after electro-Fenton treatment and had a recycling perspective.</p></div>","PeriodicalId":23714,"journal":{"name":"Water Resources and Industry","volume":"31 ","pages":"Article 100256"},"PeriodicalIF":4.5000,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2212371724000180/pdfft?md5=6a405adaba65409dbff1e728c363d9c8&pid=1-s2.0-S2212371724000180-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Fenton and electro-Fenton treatment for industrial textile wastewater recycling. Comparison of by-products removal, biodegradability, toxicity, and re-dyeing\",\"authors\":\"Magdalena Sobczak , Sebastian Bujnowicz , Lucyna Bilińska\",\"doi\":\"10.1016/j.wri.2024.100256\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A comparative study of the results obtained from using Fenton and electro-Fenton processes in textile wastewater treatment is presented. Global indicators, color, COD, TOC, and BOD<sub>5</sub> were employed to investigate the treatments. Examination of the representative by-products gave new insights into Fenton. Even though the color removal was higher for classical Fenton (almost 100% color removal) than for electro-Fenton, the overall purification effect was not directly advantageous for Fenton. We found that electro-Fenton removed COD and TOC more efficiently. The biodegradability BI (BOD<sub>5</sub>/COD) parameter was investigated, where the textile wastewater was hardly biodegradable (BI was 0.12 ± 0.007). BI of Fenton was also low (0.044 ± 0.006). Electro-Fenton yielded a considerably more promising result, where BI was 0.83 ± 0.15, and proved more bio-friendly than classical Fenton. Additionally, electro-Fenton was more efficient in by-product removal, especially the naphthalic component, with 90% removal (while Fenton removed 50%). The by-products influenced the after-treatment toxicity assessment of <em>V. fischeri.</em> The EC<sub>50</sub> values were below 2% and even lower for electro-Fenton. The results of the color matching parameters (DE<sub>CMC</sub>) of re-dyeing were unacceptable using after-Fenton water at 8.66. DE<sub>CMC</sub> results were between 1.01 and 2.71 after electro-Fenton treatment and had a recycling perspective.</p></div>\",\"PeriodicalId\":23714,\"journal\":{\"name\":\"Water Resources and Industry\",\"volume\":\"31 \",\"pages\":\"Article 100256\"},\"PeriodicalIF\":4.5000,\"publicationDate\":\"2024-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2212371724000180/pdfft?md5=6a405adaba65409dbff1e728c363d9c8&pid=1-s2.0-S2212371724000180-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Water Resources and Industry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2212371724000180\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"WATER RESOURCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water Resources and Industry","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2212371724000180","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"WATER RESOURCES","Score":null,"Total":0}
Fenton and electro-Fenton treatment for industrial textile wastewater recycling. Comparison of by-products removal, biodegradability, toxicity, and re-dyeing
A comparative study of the results obtained from using Fenton and electro-Fenton processes in textile wastewater treatment is presented. Global indicators, color, COD, TOC, and BOD5 were employed to investigate the treatments. Examination of the representative by-products gave new insights into Fenton. Even though the color removal was higher for classical Fenton (almost 100% color removal) than for electro-Fenton, the overall purification effect was not directly advantageous for Fenton. We found that electro-Fenton removed COD and TOC more efficiently. The biodegradability BI (BOD5/COD) parameter was investigated, where the textile wastewater was hardly biodegradable (BI was 0.12 ± 0.007). BI of Fenton was also low (0.044 ± 0.006). Electro-Fenton yielded a considerably more promising result, where BI was 0.83 ± 0.15, and proved more bio-friendly than classical Fenton. Additionally, electro-Fenton was more efficient in by-product removal, especially the naphthalic component, with 90% removal (while Fenton removed 50%). The by-products influenced the after-treatment toxicity assessment of V. fischeri. The EC50 values were below 2% and even lower for electro-Fenton. The results of the color matching parameters (DECMC) of re-dyeing were unacceptable using after-Fenton water at 8.66. DECMC results were between 1.01 and 2.71 after electro-Fenton treatment and had a recycling perspective.
期刊介绍：
Water Resources and Industry moves research to innovation by focusing on the role industry plays in the exploitation, management and treatment of water resources. Different industries use radically different water resources in their production processes, while they produce, treat and dispose a wide variety of wastewater qualities. Depending on the geographical location of the facilities, the impact on the local resources will vary, pre-empting the applicability of one single approach. The aims and scope of the journal include: -Industrial water footprint assessment - an evaluation of tools and methodologies -What constitutes good corporate governance and policy and how to evaluate water-related risk -What constitutes good stakeholder collaboration and engagement -New technologies enabling companies to better manage water resources -Integration of water and energy and of water treatment and production processes in industry
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