含绿色溶剂体系的气液平衡:政治评论

IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY
Priyank Khirsariya, V. Parsana
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引用次数: 0

摘要

蒸馏塔的设计和操作是以汽液平衡数据为基础的,这是化学工业所必需的。近年来,化学工业开始追求绿色化学和可持续发展。此外,绿色溶剂比传统溶剂更环保、更清洁,因此是一种很好的替代品。文献中关于生成包含绿色溶剂的体系的等压/等温汽液平衡(VLE)数据的报道非常有限。本文探讨了三种新兴绿色溶剂的 VLE 数据,如环戊基甲基醚 (CPME)、γ-戊内酯 (GVL) 和 2-甲基四氢呋喃 (2-MeTHF)。新出现的绿色溶剂具有良好的环境、健康和安全特性,使其在广泛的应用中成为具有吸引力的替代品。本研究侧重于两个关键分离过程:从 Power-to-X 化学过程中萃取甲酸,以及从化学合成或发酵过程中提纯醋酸。为了促进这些分离,这些绿色溶剂与醋酸/甲酸系统的精确 VLE 数据至关重要。本文回顾了与涉及这些绿色溶剂体系的 VLE 数据相关的文献。研究人员在对包含这三种绿色溶剂的体系进行 VLE 实验和建模之前,可以参考这些信息。此外,本文还概述了绿色溶剂的最新研究及其应用,说明了它们在各种工业流程中的多功能性和潜力。需要努力开展研究,为绿色溶剂体系生成 VLE 数据,并支持化学工业向更可持续的做法过渡。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Vapor-Liquid Equilibrium of System Comprising Green Solvents: A Holistic Review
The design and operation of distillation columns is based on vapor-liquid equilibrium data, which is a necessity for the chemical industry. In recent years, chemical industry has embraced green chemistry and sustainable development. Furthermore, green solvents are more environmentfriendly and cleaner than conventional solvents and thus offer a good alternative. Very limited work has been reported in the literature that focuses on the generation of isobaric/isothermal vapor-liquid equilibrium (VLE) data of systems comprising green solvents. In this paper, reported VLE data are explored for three emerging green solvents, such as cyclopentyl methyl ether (CPME), γ- valerolactone (GVL), and 2-methyltetrahydrofuran (2-MeTHF). Emerging green solvents have favorable environmental, health, and safety characteristics, making them attractive alternatives for a wide range of applications. The study focuses on two critical separations; the extraction of formic acid from Power-to-X chemical processes and purification of acetic acid from chemical synthesis or fermentation processes. Both processes are integral parts of the chemical industry's sustainable development. To facilitate these separations, accurate VLE data for these green solvents with acetic acid/formic acid systems are essential. The paper reviews literature related to VLE data for systems involving these green solvents. It provides insights into the experimental conditions, equipment, analysis methods, thermodynamic models, and error-minimizing functions used in the previous studies. The researchers can refer to this information as a useful reference prior to the VLE experimentation and modeling of systems comprising these three green solvents. Moreover, the paper presents an overview of recent research on green solvents and their applications, illustrating their versatility and potential for various industrial processes. Research efforts are needed to generate VLE data for green solvent systems and support the chemical industry in transitions towards more sustainable practices.
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来源期刊
Current Green Chemistry
Current Green Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
4.30
自引率
13.60%
发文量
6
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