{"title":"含绿色溶剂体系的气液平衡:政治评论","authors":"Priyank Khirsariya, V. Parsana","doi":"10.2174/0122133461272026231101094324","DOIUrl":null,"url":null,"abstract":"\n\nThe design and operation of distillation columns is based on vapor-liquid equilibrium\ndata, which is a necessity for the chemical industry. In recent years, chemical industry has embraced\ngreen chemistry and sustainable development. Furthermore, green solvents are more environmentfriendly\nand cleaner than conventional solvents and thus offer a good alternative. Very limited work\nhas been reported in the literature that focuses on the generation of isobaric/isothermal vapor-liquid\nequilibrium (VLE) data of systems comprising green solvents. In this paper, reported VLE data are\nexplored for three emerging green solvents, such as cyclopentyl methyl ether (CPME), γ-\nvalerolactone (GVL), and 2-methyltetrahydrofuran (2-MeTHF). Emerging green solvents have favorable\nenvironmental, health, and safety characteristics, making them attractive alternatives for a\nwide range of applications. The study focuses on two critical separations; the extraction of formic\nacid from Power-to-X chemical processes and purification of acetic acid from chemical synthesis or\nfermentation processes. Both processes are integral parts of the chemical industry's sustainable development.\nTo facilitate these separations, accurate VLE data for these green solvents with acetic\nacid/formic acid systems are essential. The paper reviews literature related to VLE data for systems\ninvolving these green solvents. It provides insights into the experimental conditions, equipment,\nanalysis methods, thermodynamic models, and error-minimizing functions used in the previous studies.\nThe researchers can refer to this information as a useful reference prior to the VLE experimentation\nand modeling of systems comprising these three green solvents. Moreover, the paper presents an\noverview of recent research on green solvents and their applications, illustrating their versatility and\npotential for various industrial processes. Research efforts are needed to generate VLE data for green\nsolvent systems and support the chemical industry in transitions towards more sustainable practices.\n","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":"51 9","pages":""},"PeriodicalIF":16.4000,"publicationDate":"2024-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Vapor-Liquid Equilibrium of System Comprising Green Solvents: A\\nHolistic Review\",\"authors\":\"Priyank Khirsariya, V. Parsana\",\"doi\":\"10.2174/0122133461272026231101094324\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n\\nThe design and operation of distillation columns is based on vapor-liquid equilibrium\\ndata, which is a necessity for the chemical industry. In recent years, chemical industry has embraced\\ngreen chemistry and sustainable development. Furthermore, green solvents are more environmentfriendly\\nand cleaner than conventional solvents and thus offer a good alternative. Very limited work\\nhas been reported in the literature that focuses on the generation of isobaric/isothermal vapor-liquid\\nequilibrium (VLE) data of systems comprising green solvents. In this paper, reported VLE data are\\nexplored for three emerging green solvents, such as cyclopentyl methyl ether (CPME), γ-\\nvalerolactone (GVL), and 2-methyltetrahydrofuran (2-MeTHF). Emerging green solvents have favorable\\nenvironmental, health, and safety characteristics, making them attractive alternatives for a\\nwide range of applications. The study focuses on two critical separations; the extraction of formic\\nacid from Power-to-X chemical processes and purification of acetic acid from chemical synthesis or\\nfermentation processes. Both processes are integral parts of the chemical industry's sustainable development.\\nTo facilitate these separations, accurate VLE data for these green solvents with acetic\\nacid/formic acid systems are essential. The paper reviews literature related to VLE data for systems\\ninvolving these green solvents. It provides insights into the experimental conditions, equipment,\\nanalysis methods, thermodynamic models, and error-minimizing functions used in the previous studies.\\nThe researchers can refer to this information as a useful reference prior to the VLE experimentation\\nand modeling of systems comprising these three green solvents. Moreover, the paper presents an\\noverview of recent research on green solvents and their applications, illustrating their versatility and\\npotential for various industrial processes. Research efforts are needed to generate VLE data for green\\nsolvent systems and support the chemical industry in transitions towards more sustainable practices.\\n\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":\"51 9\",\"pages\":\"\"},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-01-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2174/0122133461272026231101094324\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/0122133461272026231101094324","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Vapor-Liquid Equilibrium of System Comprising Green Solvents: A
Holistic Review
The design and operation of distillation columns is based on vapor-liquid equilibrium
data, which is a necessity for the chemical industry. In recent years, chemical industry has embraced
green chemistry and sustainable development. Furthermore, green solvents are more environmentfriendly
and cleaner than conventional solvents and thus offer a good alternative. Very limited work
has been reported in the literature that focuses on the generation of isobaric/isothermal vapor-liquid
equilibrium (VLE) data of systems comprising green solvents. In this paper, reported VLE data are
explored for three emerging green solvents, such as cyclopentyl methyl ether (CPME), γ-
valerolactone (GVL), and 2-methyltetrahydrofuran (2-MeTHF). Emerging green solvents have favorable
environmental, health, and safety characteristics, making them attractive alternatives for a
wide range of applications. The study focuses on two critical separations; the extraction of formic
acid from Power-to-X chemical processes and purification of acetic acid from chemical synthesis or
fermentation processes. Both processes are integral parts of the chemical industry's sustainable development.
To facilitate these separations, accurate VLE data for these green solvents with acetic
acid/formic acid systems are essential. The paper reviews literature related to VLE data for systems
involving these green solvents. It provides insights into the experimental conditions, equipment,
analysis methods, thermodynamic models, and error-minimizing functions used in the previous studies.
The researchers can refer to this information as a useful reference prior to the VLE experimentation
and modeling of systems comprising these three green solvents. Moreover, the paper presents an
overview of recent research on green solvents and their applications, illustrating their versatility and
potential for various industrial processes. Research efforts are needed to generate VLE data for green
solvent systems and support the chemical industry in transitions towards more sustainable practices.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.