{"title":"用于水处理的多孔高岭土/共铁氧体的物理和结构特性","authors":"Wasan Ziedan, Mukhlis Ismail, Wafaa A. Hussain","doi":"10.53293/jasn.2024.7103.1245","DOIUrl":null,"url":null,"abstract":"Aqueous solutions with heavy metals such as Cr (VI), Pb, and Cd (II) can have an adverse effect on human health because of their toxicity. As a result, it is important to remove these heavy metals from the aquatic environment to save the human healthy. X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and field-emission scanning electron microscopy (FE-SEM) used in this research to characterize cobalt ferrite (CoFe 2 O 4 ) nanoparticles and confirm the structure of Co-Fe 2 O 4 . These particles were used to make porous samples and burned at 1050 °C in mixtures of (0, 3, 5, 7, and 10) wt.% of cobalt ferrite and kaolin with 20 wt.% of charcoal. These samples serve as adsorbents that remove Pb from the wastewater. The highest rates of removal were confirmed using various treatments at (pH 3, 7, and 9). A Williamson-Hall plot was used to determine the crystal size (33) nm. The FT-IR spectra exhibited spinel-ferrite characteristics. Studies using FE-SEM demonstrated that the sample was in Nano crystalline. Using a vibrating sample magnetometer (VSM), different magnetic properties are taken from the hysteresis loops such as saturation magnetization (Ms) and remanence (Mr) and coercivity (","PeriodicalId":15241,"journal":{"name":"Journal of Applied Sciences and Nanotechnology","volume":"23 ","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Physical and Structural Properties of Porous Kaolin/Co-Ferrite for Water Treatment\",\"authors\":\"Wasan Ziedan, Mukhlis Ismail, Wafaa A. Hussain\",\"doi\":\"10.53293/jasn.2024.7103.1245\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Aqueous solutions with heavy metals such as Cr (VI), Pb, and Cd (II) can have an adverse effect on human health because of their toxicity. As a result, it is important to remove these heavy metals from the aquatic environment to save the human healthy. X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and field-emission scanning electron microscopy (FE-SEM) used in this research to characterize cobalt ferrite (CoFe 2 O 4 ) nanoparticles and confirm the structure of Co-Fe 2 O 4 . These particles were used to make porous samples and burned at 1050 °C in mixtures of (0, 3, 5, 7, and 10) wt.% of cobalt ferrite and kaolin with 20 wt.% of charcoal. These samples serve as adsorbents that remove Pb from the wastewater. The highest rates of removal were confirmed using various treatments at (pH 3, 7, and 9). A Williamson-Hall plot was used to determine the crystal size (33) nm. The FT-IR spectra exhibited spinel-ferrite characteristics. Studies using FE-SEM demonstrated that the sample was in Nano crystalline. Using a vibrating sample magnetometer (VSM), different magnetic properties are taken from the hysteresis loops such as saturation magnetization (Ms) and remanence (Mr) and coercivity (\",\"PeriodicalId\":15241,\"journal\":{\"name\":\"Journal of Applied Sciences and Nanotechnology\",\"volume\":\"23 \",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Sciences and Nanotechnology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.53293/jasn.2024.7103.1245\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Sciences and Nanotechnology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.53293/jasn.2024.7103.1245","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
含有铬 (VI)、铅和镉 (II) 等重金属的水溶液因其毒性会对人类健康产生不利影响。因此,从水环境中去除这些重金属以保护人类健康非常重要。本研究利用 X 射线衍射(XRD)、傅立叶变换红外光谱(FTIR)和场发射扫描电子显微镜(FE-SEM)来表征钴铁氧体(CoFe 2 O 4 )纳米粒子,并确认 Co-Fe 2 O 4 的结构。这些颗粒被用来制作多孔样品,并在 1050 °C的温度下在重量百分比为(0、3、5、7 和 10)的钴铁氧体和高岭土与 20 重量百分比的木炭的混合物中燃烧。这些样品可作为吸附剂去除废水中的铅。在(pH 值为 3、7 和 9)的不同处理条件下,确认了最高的去除率。利用威廉森-霍尔图确定了晶体尺寸 (33) nm。傅立叶变换红外光谱显示出尖晶石-铁氧体特征。使用 FE-SEM 进行的研究表明,样品为纳米结晶。利用振动样品磁力计(VSM)从磁滞回线中提取了不同的磁特性,如饱和磁化(Ms)和剩磁(Mr)以及矫顽力(Coercivity)。
Physical and Structural Properties of Porous Kaolin/Co-Ferrite for Water Treatment
Aqueous solutions with heavy metals such as Cr (VI), Pb, and Cd (II) can have an adverse effect on human health because of their toxicity. As a result, it is important to remove these heavy metals from the aquatic environment to save the human healthy. X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and field-emission scanning electron microscopy (FE-SEM) used in this research to characterize cobalt ferrite (CoFe 2 O 4 ) nanoparticles and confirm the structure of Co-Fe 2 O 4 . These particles were used to make porous samples and burned at 1050 °C in mixtures of (0, 3, 5, 7, and 10) wt.% of cobalt ferrite and kaolin with 20 wt.% of charcoal. These samples serve as adsorbents that remove Pb from the wastewater. The highest rates of removal were confirmed using various treatments at (pH 3, 7, and 9). A Williamson-Hall plot was used to determine the crystal size (33) nm. The FT-IR spectra exhibited spinel-ferrite characteristics. Studies using FE-SEM demonstrated that the sample was in Nano crystalline. Using a vibrating sample magnetometer (VSM), different magnetic properties are taken from the hysteresis loops such as saturation magnetization (Ms) and remanence (Mr) and coercivity (