优化 CF/PEKK 复合材料的粘合性能:红外加热和加压固化的作用

Kang-Min Kim, Sanjay Kumar, Yun-Hae Kim
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引用次数: 0

摘要

碳纤维/聚醚醚酮酮(CF/PEKK)层压板的粘结性能与结晶度密切相关,并受球泡体的生长、形成和密度的影响。与烘箱固结相比,压力固结具有调节压力的能力,因此质量更优。然而,使用压制固结法粘合和生产 CF/PEKK 层压材料时,质量会因成型条件的不同而有很大差异。目前,使用压机固结法生产 CF/PEKK 层压板的研究十分活跃,但对 CF/PEKK 层压板的共固结研究却十分缺乏。因此,在本研究中,为实现 CF/PEKK 的优异粘合性能,对压机固结的成型工艺变量进行了确定。此外,还采用了红外加热辅助表面热处理,通过控制结晶度和球形颗粒来提高 CF/PEKK 层压材料的粘合性能。为了分析粘合性能,进行了短豆剪切试验,以获得层间剪切强度(ILSS)。结果表明,通过红外加热进行表面改性可提高结晶度,并明显增大球粒尺寸。在特定条件下,还观察到粘结性能得到改善。据判断,这主要是由于通过红外加热进行表面处理和加压固结的特定条件增加了粘合界面的球形颗粒尺寸和结晶度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Optimizing bonding performance in CF/PEKK composites: The role of IR heating and press consolidation
Bonding performance of carbon fiber/polyetherketoneketone (CF/PEKK) laminates is closely related to crystallinity and is influenced by growth, formation, and density of spherulites. Press consolidation, with its ability to adjust pressure, exhibits superior quality compared to oven consolidation. However, bonding and production of CF/PEKK laminates using Press consolidation exhibit significant variations in quality depending on forming conditions. While research on producing CF/PEKK laminates using press consolidation is currently active, there is a lack of studies on co-consolidation for CF/PEKK laminates. Thus, in this study, establishment of forming process variables for press consolidation was conducted to achieve excellent bonding performance for CF/PEKK. Furthermore, IR heating-assisted surface heat treatment was employed to enhance bonding performance of CF/PEKK laminates by controlling crystallinity and spherulites. To analyze bonding performance, short bean shear testing was conducted to obtain interlaminar shear strength (ILSS). Results showed that surface modification through IR heating led to an increase in crystallinity and a noticeable growth in size of spherulites. In specific conditions, improved bonding performance was observed. This is judged to be primarily due to increase in spherulite size and crystallinity at bonding interface, attributed to specific conditions of both surface treatment through IR heating and Press consolidation.
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