基于 Cu/ZnO/Al2O3 催化剂的甲醇合成之谜。

IF 55.8 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Arik Beck*, Mark A. Newton*, Leon G. A. van de Water* and Jeroen A. van Bokhoven*, 
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引用次数: 0

摘要

用于以 CO/CO2/H2 为原料合成甲醇的 Cu/ZnO/Al2O3 (CZA) 催化剂配方的活性和耐久性远远超过其单个组分的总和。因此,这种三元催化体系是催化协同作用的典型范例,自 20 世纪 60 年代中期问世以来,一直被用于甲醇的大规模商业化生产,对其原始配方的改动微乎其微。甲醇是化学工业的重要组成部分。它也是一种极具吸引力的储能分子,也可以仅从 CO2 和 H2 中生产,从而有效利用封存的 CO2。因此,这种有点不同寻常的催化剂配方在现代化学工业和全球经济中发挥着巨大作用,从 20 世纪 20 年代开始的大量持续研究也证明了这一点。然而,尽管在商业上取得了巨大成功,而且几十年来,旨在了解这种配方如何发挥作用的研究一直在继续,但对这种材料如何实现其功能的全面和普遍认同的理解仍有待实现。在对 CZA 催化剂进行了将近一个世纪的研究之后,本综述旨在评估迄今为止所取得的成就,并说明该领域是如何以及在多大程度上取得了发展。为此,本综述按时间顺序评估了有关这种催化剂配方的研究,并对多年来提出的各种假设和主张的有效性和新颖性进行了批判性评估。最后,本综述试图全面总结当前文献对 CZA 催化剂协同作用基本来源的启示,并由此提出进一步推动该领域发展的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The Enigma of Methanol Synthesis by Cu/ZnO/Al2O3-Based Catalysts

The Enigma of Methanol Synthesis by Cu/ZnO/Al2O3-Based Catalysts

The Enigma of Methanol Synthesis by Cu/ZnO/Al2O3-Based Catalysts

The activity and durability of the Cu/ZnO/Al2O3 (CZA) catalyst formulation for methanol synthesis from CO/CO2/H2 feeds far exceed the sum of its individual components. As such, this ternary catalytic system is a prime example of synergy in catalysis, one that has been employed for the large scale commercial production of methanol since its inception in the mid 1960s with precious little alteration to its original formulation. Methanol is a key building block of the chemical industry. It is also an attractive energy storage molecule, which can also be produced from CO2 and H2 alone, making efficient use of sequestered CO2. As such, this somewhat unusual catalyst formulation has an enormous role to play in the modern chemical industry and the world of global economics, to which the correspondingly voluminous and ongoing research, which began in the 1920s, attests. Yet, despite this commercial success, and while research aimed at understanding how this formulation functions has continued throughout the decades, a comprehensive and universally agreed upon understanding of how this material achieves what it does has yet to be realized. After nigh on a century of research into CZA catalysts, the purpose of this Review is to appraise what has been achieved to date, and to show how, and how far, the field has evolved. To do so, this Review evaluates the research regarding this catalyst formulation in a chronological order and critically assesses the validity and novelty of various hypotheses and claims that have been made over the years. Ultimately, the Review attempts to derive a holistic summary of what the current body of literature tells us about the fundamental sources of the synergies at work within the CZA catalyst and, from this, suggest ways in which the field may yet be further advanced.

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来源期刊
Chemical Reviews
Chemical Reviews 化学-化学综合
CiteScore
106.00
自引率
1.10%
发文量
278
审稿时长
4.3 months
期刊介绍: Chemical Reviews is a highly regarded and highest-ranked journal covering the general topic of chemistry. Its mission is to provide comprehensive, authoritative, critical, and readable reviews of important recent research in organic, inorganic, physical, analytical, theoretical, and biological chemistry. Since 1985, Chemical Reviews has also published periodic thematic issues that focus on a single theme or direction of emerging research.
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