松辽盆地上白垩统青山口组页岩油的碳氢微迁移及差异富集机理

IF 1.4 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY
Geological Journal Pub Date : 2024-03-25 DOI:10.1002/gj.4952
Ziheng Guan, Qingqiang Meng, Qian Huang, Xuan Tang, Yansheng Shan, Guangxiang Liu, Shaobin Guo, Jinchuan Zhang, Xiong Cheng, Jinyu Xiong
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引用次数: 0

摘要

页岩储层即使在同一区间的较短距离内,其矿物成分和含油量也具有很强的异质性。为了更好地了解页岩油的富集机理和油气在区间内的迁移趋势,探讨其分布的主要影响因素。本文采用了多种方法,包括薄片观察、TOC(总有机质)分析、岩石热解、索氏提取、组份分离和饱和碳氢化合物的 GC-MS(气相色谱质谱)分析。页岩油样品采集自松辽盆地的一口探井,分析了页岩油夹层的分布和富集特征。结果表明,青山口地层第一层(K2qn1)可分为六个小层。从 Q1 到 Q6,岩性可分为三类:高频层状页岩、块状页岩和生物碎屑页岩。松辽盆地K2qn1的湖相基质页岩TOC中等,含油率、OM转化率较高。TOC介于1.5-4.2 wt%之间,S1介于1.4-4 mg/g之间,S2介于4-10.6 mg/g之间,Tmax介于351-497°C之间,OSI介于57-115.34 mg HC/g之间。K2qn1 的下部 Q1-Q4,以高频层状页岩为特征,含有残余页岩油;而 K2qn1 的上部 Q5 和 Q6,以生物碎屑页岩和块状泥岩为特征,以原位型页岩油为主。K2qn1 中的原油为同源油,主要发生微迁移。Q5-Q6 断面的轻质油含量最高,其他轻质组分显著的区域位于 Q1 的中段、Q2 的上段、Q3 和 Q4。Q1-Q4 主要由残余页岩油组成,而 Q5-Q6 则主要由原位页岩油组成,页岩油的主要微迁移方向发生在 Q1-Q4 的横向。各段的横向迁移主要发生在 Q3 和 Q4 的上部、Q1 和 Q2 的下部、Q5 的底部以及 Q6 与青山口地层第二层(K2qn2)的界面。块状泥岩保留了原位页岩油,尤其是轻烃。在高频层状页岩内部,存在很强的水平连通性,横向油气排出是 Q1-Q4 微迁移的主要机制。本文可为 K2qn1 地层页岩油以及中高成熟基质页岩油的迁移和差异成藏提供参考值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Hydrocarbon micro-migration and differential enrichment mechanism of shale oil in upper Cretaceous Qingshankou Formation in Songliao Basin

Hydrocarbon micro-migration and differential enrichment mechanism of shale oil in upper Cretaceous Qingshankou Formation in Songliao Basin

Hydrocarbon micro-migration and differential enrichment mechanism of shale oil in upper Cretaceous Qingshankou Formation in Songliao Basin

Shale reservoir has strong heterogeneity in mineral composition and oil content even at a short distance in the same interval. To better understand the accumulation mechanism of shale oil and hydrocarbon migration tendency in the interval, and explore the main influencing factors of distribution. This paper employed various methods, including thin-section observation, TOC (total organic matter (OM)) analysis, rock pyrolysis, Soxhlet extraction, group component separation, and GC–MS (gas chromatography mass spectrometry) analysis of saturated hydrocarbons. The shale oil samples were collected from an exploratory well in the Songliao Basin, and the distribution and enrichment characteristics of shale oil interlayers were analysed. The results show that the first member of Qingshankou Formation (K2qn1) could be divided into six small layers. From Q1 to Q6, the lithofacies could be divided into three types: high-frequency laminar shale, massive shale, and bioclastic shale. The lacustrine matrix shale of K2qn1 in Songliao Basin has medium TOC, and high oil contents, OM conversion rate. The TOC ranges from 1.5 to 4.2 wt%, S1 varies between 1.4 and 4 mg/g, S2 falls within the range of 4 to 10.6 mg/g, Tmax ranges from 351 to 497°C, and the OSI varies between 57 and 115.34 mg HC/g rock. The lower part of the K2qn1, Q1–Q4, characterized by high-frequency laminar shale, contained residual shale oil, while the upper part of the K2qn1, Q5 and Q6, characterized by bioclastic shale and massive mudstone, and are dominated by in-situ type shale oil. The crude oil in K2qn1 is homologous, and primarily undergoes micro-migration. The Q5–Q6 section has the highest light oil content, while other regions with notable light components are located in the middle of Q1, the upper sections of Q2, Q3, and Q4.Q1–Q4 are primarily composed of residual shale oil, whereas Q5–Q6 is primarily composed of in-situ shale oil, and the primary micro-migration direction of shale oil occurs laterally within Q1–Q4. The lateral migration of each section mainly occurs at the upper part of Q3 and Q4, the lower part of Q1 and Q2, the bottom of Q5, and the interface between Q6 and the second member of Qingshankou formation (K2qn2). The block mudstone retains in-situ shale oil, especially light hydrocarbons. Within the high-frequency laminar shale, there is strong horizontal connectivity, and lateral hydrocarbon expulsion serves as the primary mechanism for micro-migration in Q1–Q4. This paper can provide reference values for K2qn1 Formation shale oil and the migration and differential reservoir formation of medium and high-maturity matrix shale oil.

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来源期刊
Geological Journal
Geological Journal 地学-地球科学综合
CiteScore
4.20
自引率
11.10%
发文量
269
审稿时长
3 months
期刊介绍: In recent years there has been a growth of specialist journals within geological sciences. Nevertheless, there is an important role for a journal of an interdisciplinary kind. Traditionally, GEOLOGICAL JOURNAL has been such a journal and continues in its aim of promoting interest in all branches of the Geological Sciences, through publication of original research papers and review articles. The journal publishes Special Issues with a common theme or regional coverage e.g. Chinese Dinosaurs; Tectonics of the Eastern Mediterranean, Triassic basins of the Central and North Atlantic Borderlands). These are extensively cited. The Journal has a particular interest in publishing papers on regional case studies from any global locality which have conclusions of general interest. Such papers may emphasize aspects across the full spectrum of geological sciences.
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