Adem Rüzgar, Lokman Şener, Yaşar Karataş, Mehmet Gülcan
{"title":"分布在氧化镧（III）上的钯（0）纳米粒子是肼硼烷甲醇化制氢的有效催化剂。","authors":"Adem Rüzgar, Lokman Şener, Yaşar Karataş, Mehmet Gülcan","doi":"10.55730/1300-0527.3646","DOIUrl":null,"url":null,"abstract":"<p><p>Pd (0) nanoparticles (NPs) distributed on lanthanum (III) oxide were ex situ generated from the reduction of Pd<sup>2+</sup> ions using NaBH<sub>4</sub> as reducing agent. The Pd/La<sub>2</sub>O<sub>3</sub> displayed good catalytic activity in H<sub>2</sub>(g) releasing from the hydrazine-borane (HB) methanolysis reaction and it was identified by advanced techniques. Pd/La<sub>2</sub>O<sub>3</sub> was found to be an active catalyst procuring three equiv. H<sub>2</sub>(g) per mole of HB. The results from TEM images represent the formation of Pd (0) NPs with an average particle size of 1.94 ± 0.1 nm on the surface of La<sub>2</sub>O<sub>3</sub>. Moreover, Pd/La<sub>2</sub>O<sub>3</sub> with various Pd loadings were prepared and tested as catalyst in the methanolysis reaction to find the optimum metal loading on La<sub>2</sub>O<sub>3</sub> support. The highest H<sub>2</sub> formation rate was achieved with 3.0 wt% Pd. Pd/La<sub>2</sub>O<sub>3</sub> catalyst exhibited a turnover frequency (TOF) value of 24.4 mol H<sub>2</sub> mol Pd<sup>-1</sup> min<sup>-1</sup> in the reaction conditions. Additionally, the effect of different catalyst concentrations and temperatures on the reaction kinetics for the methanolysis of HB catalyzed by Pd/La<sub>2</sub>O<sub>3</sub>.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":"48 1","pages":"137-151"},"PeriodicalIF":1.3000,"publicationDate":"2024-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10965170/pdf/","citationCount":"0","resultStr":"{\"title\":\"Palladium (0) nanoparticles distributed on lanthanum (III) oxide as an effective catalyst for the methanolysis of hydrazine-borane to produce hydrogen.\",\"authors\":\"Adem Rüzgar, Lokman Şener, Yaşar Karataş, Mehmet Gülcan\",\"doi\":\"10.55730/1300-0527.3646\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Pd (0) nanoparticles (NPs) distributed on lanthanum (III) oxide were ex situ generated from the reduction of Pd<sup>2+</sup> ions using NaBH<sub>4</sub> as reducing agent. The Pd/La<sub>2</sub>O<sub>3</sub> displayed good catalytic activity in H<sub>2</sub>(g) releasing from the hydrazine-borane (HB) methanolysis reaction and it was identified by advanced techniques. Pd/La<sub>2</sub>O<sub>3</sub> was found to be an active catalyst procuring three equiv. H<sub>2</sub>(g) per mole of HB. The results from TEM images represent the formation of Pd (0) NPs with an average particle size of 1.94 ± 0.1 nm on the surface of La<sub>2</sub>O<sub>3</sub>. Moreover, Pd/La<sub>2</sub>O<sub>3</sub> with various Pd loadings were prepared and tested as catalyst in the methanolysis reaction to find the optimum metal loading on La<sub>2</sub>O<sub>3</sub> support. The highest H<sub>2</sub> formation rate was achieved with 3.0 wt% Pd. Pd/La<sub>2</sub>O<sub>3</sub> catalyst exhibited a turnover frequency (TOF) value of 24.4 mol H<sub>2</sub> mol Pd<sup>-1</sup> min<sup>-1</sup> in the reaction conditions. Additionally, the effect of different catalyst concentrations and temperatures on the reaction kinetics for the methanolysis of HB catalyzed by Pd/La<sub>2</sub>O<sub>3</sub>.</p>\",\"PeriodicalId\":23367,\"journal\":{\"name\":\"Turkish Journal of Chemistry\",\"volume\":\"48 1\",\"pages\":\"137-151\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2024-01-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10965170/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Turkish Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.55730/1300-0527.3646\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/1/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Turkish Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.55730/1300-0527.3646","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/1/1 0:00:00","PubModel":"eCollection","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Palladium (0) nanoparticles distributed on lanthanum (III) oxide as an effective catalyst for the methanolysis of hydrazine-borane to produce hydrogen.
Pd (0) nanoparticles (NPs) distributed on lanthanum (III) oxide were ex situ generated from the reduction of Pd2+ ions using NaBH4 as reducing agent. The Pd/La2O3 displayed good catalytic activity in H2(g) releasing from the hydrazine-borane (HB) methanolysis reaction and it was identified by advanced techniques. Pd/La2O3 was found to be an active catalyst procuring three equiv. H2(g) per mole of HB. The results from TEM images represent the formation of Pd (0) NPs with an average particle size of 1.94 ± 0.1 nm on the surface of La2O3. Moreover, Pd/La2O3 with various Pd loadings were prepared and tested as catalyst in the methanolysis reaction to find the optimum metal loading on La2O3 support. The highest H2 formation rate was achieved with 3.0 wt% Pd. Pd/La2O3 catalyst exhibited a turnover frequency (TOF) value of 24.4 mol H2 mol Pd-1 min-1 in the reaction conditions. Additionally, the effect of different catalyst concentrations and temperatures on the reaction kinetics for the methanolysis of HB catalyzed by Pd/La2O3.
期刊介绍：
The Turkish Journal of Chemistry is a bimonthly multidisciplinary journal published by the Scientific and Technological Research Council of Turkey (TÜBİTAK).
The journal is dedicated to dissemination of knowledge in all disciplines of chemistry (organic, inorganic, physical, polymeric, technical, theoretical and analytical chemistry) as well as research at the interface with other sciences especially in chemical engineering where molecular aspects are key to the findings.
The journal accepts English-language original manuscripts and contribution is open to researchers of all nationalities.
The journal publishes refereed original papers, reviews, letters to editor and issues devoted to special fields.
All manuscripts are peer-reviewed and electronic processing ensures accurate reproduction of text and data, plus publication times as short as possible.
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