具有磺酰亚胺连接体的羟基端树枝状聚合物作为具有工业重要性的金属的粘合剂。

IF 1.3 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Turkish Journal of Chemistry Pub Date : 2024-01-02 eCollection Date: 2024-01-01 DOI:10.55730/1300-0527.3641
Khaleel Abu Sbeih, Mohammad Al Harahsheh
{"title":"具有磺酰亚胺连接体的羟基端树枝状聚合物作为具有工业重要性的金属的粘合剂。","authors":"Khaleel Abu Sbeih, Mohammad Al Harahsheh","doi":"10.55730/1300-0527.3641","DOIUrl":null,"url":null,"abstract":"<p><p>First- and second-generation hydroxyl-terminated dendrimers were prepared starting from a 1,3-diaminopropane core and sulfonimide linkers. A first-generation mesitylene-derived dendrimer was also prepared with the same terminals. The dendrimers were then reacted with Fe<sup>3+</sup>, Al<sup>3+</sup>, and UO<sub>2</sub><sup>2+</sup> separately in order to apply the dendrimers for binding these metals, which have important industrial applications and pose environmental problems simultaneously. The prepared dendrimers were also shown to bind Fe<sup>3+</sup> selectively from mixtures with Al<sup>3+</sup>.</p>","PeriodicalId":23367,"journal":{"name":"Turkish Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":1.3000,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10965167/pdf/","citationCount":"0","resultStr":"{\"title\":\"Hydroxyl-terminated dendrimers with sulfonimide linkers as binders for metals of industrial significance.\",\"authors\":\"Khaleel Abu Sbeih, Mohammad Al Harahsheh\",\"doi\":\"10.55730/1300-0527.3641\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>First- and second-generation hydroxyl-terminated dendrimers were prepared starting from a 1,3-diaminopropane core and sulfonimide linkers. A first-generation mesitylene-derived dendrimer was also prepared with the same terminals. The dendrimers were then reacted with Fe<sup>3+</sup>, Al<sup>3+</sup>, and UO<sub>2</sub><sup>2+</sup> separately in order to apply the dendrimers for binding these metals, which have important industrial applications and pose environmental problems simultaneously. The prepared dendrimers were also shown to bind Fe<sup>3+</sup> selectively from mixtures with Al<sup>3+</sup>.</p>\",\"PeriodicalId\":23367,\"journal\":{\"name\":\"Turkish Journal of Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2024-01-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10965167/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Turkish Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.55730/1300-0527.3641\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/1/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Turkish Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.55730/1300-0527.3641","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/1/1 0:00:00","PubModel":"eCollection","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

以 1,3-二氨基丙烷核心和磺酰亚胺连接体为起点,制备了第一代和第二代羟基端树枝状聚合物。此外,还用相同的末端制备了第一代间二甲苯衍生树枝状聚合物。然后分别将树枝状聚合物与 Fe3+、Al3+ 和 UO22+ 反应,以便将树枝状聚合物用于结合这些金属,因为这些金属具有重要的工业应用价值,同时也带来环境问题。制备的树枝状聚合物还能从与 Al3+ 的混合物中选择性地结合 Fe3+。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Hydroxyl-terminated dendrimers with sulfonimide linkers as binders for metals of industrial significance.

First- and second-generation hydroxyl-terminated dendrimers were prepared starting from a 1,3-diaminopropane core and sulfonimide linkers. A first-generation mesitylene-derived dendrimer was also prepared with the same terminals. The dendrimers were then reacted with Fe3+, Al3+, and UO22+ separately in order to apply the dendrimers for binding these metals, which have important industrial applications and pose environmental problems simultaneously. The prepared dendrimers were also shown to bind Fe3+ selectively from mixtures with Al3+.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Turkish Journal of Chemistry
Turkish Journal of Chemistry 化学-工程:化工
CiteScore
2.40
自引率
7.10%
发文量
87
审稿时长
3 months
期刊介绍: The Turkish Journal of Chemistry is a bimonthly multidisciplinary journal published by the Scientific and Technological Research Council of Turkey (TÜBİTAK). The journal is dedicated to dissemination of knowledge in all disciplines of chemistry (organic, inorganic, physical, polymeric, technical, theoretical and analytical chemistry) as well as research at the interface with other sciences especially in chemical engineering where molecular aspects are key to the findings. The journal accepts English-language original manuscripts and contribution is open to researchers of all nationalities. The journal publishes refereed original papers, reviews, letters to editor and issues devoted to special fields. All manuscripts are peer-reviewed and electronic processing ensures accurate reproduction of text and data, plus publication times as short as possible.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信