Mahmoud Motasim , Salih Aydoğan , Tevfik Agacayak , Yasin Ramazan Eker , Amin El-gak , Ahmed A.S. Seifelnassr
{"title":"利用转盘法研究氟化钠对柠檬酸溶液中金属钛溶解动力学的影响","authors":"Mahmoud Motasim , Salih Aydoğan , Tevfik Agacayak , Yasin Ramazan Eker , Amin El-gak , Ahmed A.S. Seifelnassr","doi":"10.1016/j.hydromet.2024.106297","DOIUrl":null,"url":null,"abstract":"<div><p>This study reports the effect of sodium fluoride on the dissolution kinetics of pure metallic titanium in a citric acid solution. The effects of sodium fluoride concentration, citric acid concentration, temperature, stirring speed, and disc surface area were examined. The dissolution rate of titanium increases strongly with increasing citric acid and sodium fluoride concentrations. Fluoride ions react with hydrogen ions to form hydrofluoric acid, which removes the passive layer of titanium dioxide. An increase in the concentration of NaF and acid causes the formation of a brown layer on the surface of titanium. X-ray diffraction and SEM-EDX analyses showed that the layer composition is mostly of titanium fluoride (TiF<sub>3</sub>) and titanium fluoride oxide (TiOF<sub>2</sub>). A mixed kinetic model with an activation energy of 26.4 kJ/mol can be used to explain the reaction kinetics.</p></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"226 ","pages":"Article 106297"},"PeriodicalIF":4.8000,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The influence of sodium fluoride on the dissolution kinetics of metallic titanium in citric acid solution using the rotating disc method\",\"authors\":\"Mahmoud Motasim , Salih Aydoğan , Tevfik Agacayak , Yasin Ramazan Eker , Amin El-gak , Ahmed A.S. Seifelnassr\",\"doi\":\"10.1016/j.hydromet.2024.106297\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This study reports the effect of sodium fluoride on the dissolution kinetics of pure metallic titanium in a citric acid solution. The effects of sodium fluoride concentration, citric acid concentration, temperature, stirring speed, and disc surface area were examined. The dissolution rate of titanium increases strongly with increasing citric acid and sodium fluoride concentrations. Fluoride ions react with hydrogen ions to form hydrofluoric acid, which removes the passive layer of titanium dioxide. An increase in the concentration of NaF and acid causes the formation of a brown layer on the surface of titanium. X-ray diffraction and SEM-EDX analyses showed that the layer composition is mostly of titanium fluoride (TiF<sub>3</sub>) and titanium fluoride oxide (TiOF<sub>2</sub>). A mixed kinetic model with an activation energy of 26.4 kJ/mol can be used to explain the reaction kinetics.</p></div>\",\"PeriodicalId\":13193,\"journal\":{\"name\":\"Hydrometallurgy\",\"volume\":\"226 \",\"pages\":\"Article 106297\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2024-03-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Hydrometallurgy\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0304386X24000379\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Hydrometallurgy","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0304386X24000379","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
The influence of sodium fluoride on the dissolution kinetics of metallic titanium in citric acid solution using the rotating disc method
This study reports the effect of sodium fluoride on the dissolution kinetics of pure metallic titanium in a citric acid solution. The effects of sodium fluoride concentration, citric acid concentration, temperature, stirring speed, and disc surface area were examined. The dissolution rate of titanium increases strongly with increasing citric acid and sodium fluoride concentrations. Fluoride ions react with hydrogen ions to form hydrofluoric acid, which removes the passive layer of titanium dioxide. An increase in the concentration of NaF and acid causes the formation of a brown layer on the surface of titanium. X-ray diffraction and SEM-EDX analyses showed that the layer composition is mostly of titanium fluoride (TiF3) and titanium fluoride oxide (TiOF2). A mixed kinetic model with an activation energy of 26.4 kJ/mol can be used to explain the reaction kinetics.
期刊介绍：
Hydrometallurgy aims to compile studies on novel processes, process design, chemistry, modelling, control, economics and interfaces between unit operations, and to provide a forum for discussions on case histories and operational difficulties.
Topics covered include: leaching of metal values by chemical reagents or bacterial action at ambient or elevated pressures and temperatures; separation of solids from leach liquors; removal of impurities and recovery of metal values by precipitation, ion exchange, solvent extraction, gaseous reduction, cementation, electro-winning and electro-refining; pre-treatment of ores by roasting or chemical treatments such as halogenation or reduction; recycling of reagents and treatment of effluents.
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