Lu Ye, Changning Ran, Zhihui Xie, Jianjun Zhang* and Sude Ma*,
{"title":"核壳 BaTiO3@SiO2 显著增强聚偏氟乙烯/聚酰亚胺基纳米复合材料的能量密度","authors":"Lu Ye, Changning Ran, Zhihui Xie, Jianjun Zhang* and Sude Ma*, ","doi":"10.1021/acs.langmuir.4c00417","DOIUrl":null,"url":null,"abstract":"<p >Improving the limited energy storage capacity of dielectric materials has long been an attractive challenge. In this work, a four-phase hybridized nanocomposite was designed. The linear polymer polyimide (PI) was added to the ferroelectric polymer polyvinylidene fluoride (PVDF) and compounded with a nanoceramic BT@SiO<sub>2</sub> with a core–shell structure. The results show that PVDF–PI/BT@SiO<sub>2</sub> nanocomposites prepared by a straightforward spin-coating method have a significantly increased discharge energy density. The polymer blends obtain a tightly extended conformation in the amorphous region. Also, this provides an excellent matrix environment for the homogeneous dispersion of fillers. The core–shell structure, as a physical barrier, not only hinders the expansion of the breakdown path but also extends multiple polarization surfaces with gradient variations at the microscopic level. Therefore, the synergistic effect generated by polymer blending and core–shell structure effectively enhances the dielectric and stored energy characteristics of nanocomposites. The dielectric constant is stable at 11.39–18.7, and the dielectric loss is always lower than 0.136. The discharge energy density is 2.5 J/cm<sup>3</sup>, almost 110% higher than that of the BOPP films (about 1.2 J/cm<sup>3</sup>). These experimental results suggest that the composite system using core–shell structure and polymer blending is a new way to improve the energy density of dielectric materials.</p>","PeriodicalId":50,"journal":{"name":"Langmuir","volume":"40 14","pages":"7710–7722"},"PeriodicalIF":3.7000,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Significantly Enhanced Energy Density of Polyvinylidene Fluoride/Polyimide-Based Nanocomposites by Core–Shell BaTiO3@SiO2\",\"authors\":\"Lu Ye, Changning Ran, Zhihui Xie, Jianjun Zhang* and Sude Ma*, \",\"doi\":\"10.1021/acs.langmuir.4c00417\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Improving the limited energy storage capacity of dielectric materials has long been an attractive challenge. In this work, a four-phase hybridized nanocomposite was designed. The linear polymer polyimide (PI) was added to the ferroelectric polymer polyvinylidene fluoride (PVDF) and compounded with a nanoceramic BT@SiO<sub>2</sub> with a core–shell structure. The results show that PVDF–PI/BT@SiO<sub>2</sub> nanocomposites prepared by a straightforward spin-coating method have a significantly increased discharge energy density. The polymer blends obtain a tightly extended conformation in the amorphous region. Also, this provides an excellent matrix environment for the homogeneous dispersion of fillers. The core–shell structure, as a physical barrier, not only hinders the expansion of the breakdown path but also extends multiple polarization surfaces with gradient variations at the microscopic level. Therefore, the synergistic effect generated by polymer blending and core–shell structure effectively enhances the dielectric and stored energy characteristics of nanocomposites. The dielectric constant is stable at 11.39–18.7, and the dielectric loss is always lower than 0.136. The discharge energy density is 2.5 J/cm<sup>3</sup>, almost 110% higher than that of the BOPP films (about 1.2 J/cm<sup>3</sup>). These experimental results suggest that the composite system using core–shell structure and polymer blending is a new way to improve the energy density of dielectric materials.</p>\",\"PeriodicalId\":50,\"journal\":{\"name\":\"Langmuir\",\"volume\":\"40 14\",\"pages\":\"7710–7722\"},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2024-03-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Langmuir\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.langmuir.4c00417\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Langmuir","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.langmuir.4c00417","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Significantly Enhanced Energy Density of Polyvinylidene Fluoride/Polyimide-Based Nanocomposites by Core–Shell BaTiO3@SiO2
Improving the limited energy storage capacity of dielectric materials has long been an attractive challenge. In this work, a four-phase hybridized nanocomposite was designed. The linear polymer polyimide (PI) was added to the ferroelectric polymer polyvinylidene fluoride (PVDF) and compounded with a nanoceramic BT@SiO2 with a core–shell structure. The results show that PVDF–PI/BT@SiO2 nanocomposites prepared by a straightforward spin-coating method have a significantly increased discharge energy density. The polymer blends obtain a tightly extended conformation in the amorphous region. Also, this provides an excellent matrix environment for the homogeneous dispersion of fillers. The core–shell structure, as a physical barrier, not only hinders the expansion of the breakdown path but also extends multiple polarization surfaces with gradient variations at the microscopic level. Therefore, the synergistic effect generated by polymer blending and core–shell structure effectively enhances the dielectric and stored energy characteristics of nanocomposites. The dielectric constant is stable at 11.39–18.7, and the dielectric loss is always lower than 0.136. The discharge energy density is 2.5 J/cm3, almost 110% higher than that of the BOPP films (about 1.2 J/cm3). These experimental results suggest that the composite system using core–shell structure and polymer blending is a new way to improve the energy density of dielectric materials.
期刊介绍:
Langmuir is an interdisciplinary journal publishing articles in the following subject categories:
Colloids: surfactants and self-assembly, dispersions, emulsions, foams
Interfaces: adsorption, reactions, films, forces
Biological Interfaces: biocolloids, biomolecular and biomimetic materials
Materials: nano- and mesostructured materials, polymers, gels, liquid crystals
Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry
Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals
However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do?
Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*.
This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).