{"title":"超越二氧化碳还原：生产有机氮化合物的电化学 C-N 偶联反应","authors":"Dohun Kim , Jungsu Eo , Seolha Lim, Dae-Hyun Nam","doi":"10.1016/j.coelec.2024.101491","DOIUrl":null,"url":null,"abstract":"<div><p>The electrosynthesis of organonitrogen compounds via co-reduction of carbon dioxide (CO<sub>2</sub>) and nitrogenous molecules is regarded as a promising green technology for sustainable and reliable chemical production. Although many researchers have reported on electrochemical C–N coupling reactions, these reactions are still insufficient for use in the commercial industry. In this work, we provide a comprehensive review of the fundamental reaction mechanism of electrochemical C–N coupling and strategies for improving the electrosynthesis of organonitrogen compounds. Additionally, we discuss the current challenges, extended electrochemical coupling reactions, and future roadmaps of electrochemical C–N coupling reactions. This review will strongly enhance the understanding of electrochemical C–N coupling reactions and propose a way forward for the electrosynthesis of organonitrogen compounds.</p></div>","PeriodicalId":11028,"journal":{"name":"Current Opinion in Electrochemistry","volume":"46 ","pages":"Article 101491"},"PeriodicalIF":7.9000,"publicationDate":"2024-03-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Beyond CO2 reduction: Electrochemical C–N coupling reaction for organonitrogen compound production\",\"authors\":\"Dohun Kim , Jungsu Eo , Seolha Lim, Dae-Hyun Nam\",\"doi\":\"10.1016/j.coelec.2024.101491\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The electrosynthesis of organonitrogen compounds via co-reduction of carbon dioxide (CO<sub>2</sub>) and nitrogenous molecules is regarded as a promising green technology for sustainable and reliable chemical production. Although many researchers have reported on electrochemical C–N coupling reactions, these reactions are still insufficient for use in the commercial industry. In this work, we provide a comprehensive review of the fundamental reaction mechanism of electrochemical C–N coupling and strategies for improving the electrosynthesis of organonitrogen compounds. Additionally, we discuss the current challenges, extended electrochemical coupling reactions, and future roadmaps of electrochemical C–N coupling reactions. This review will strongly enhance the understanding of electrochemical C–N coupling reactions and propose a way forward for the electrosynthesis of organonitrogen compounds.</p></div>\",\"PeriodicalId\":11028,\"journal\":{\"name\":\"Current Opinion in Electrochemistry\",\"volume\":\"46 \",\"pages\":\"Article 101491\"},\"PeriodicalIF\":7.9000,\"publicationDate\":\"2024-03-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Current Opinion in Electrochemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2451910324000528\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Opinion in Electrochemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2451910324000528","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Beyond CO2 reduction: Electrochemical C–N coupling reaction for organonitrogen compound production
The electrosynthesis of organonitrogen compounds via co-reduction of carbon dioxide (CO2) and nitrogenous molecules is regarded as a promising green technology for sustainable and reliable chemical production. Although many researchers have reported on electrochemical C–N coupling reactions, these reactions are still insufficient for use in the commercial industry. In this work, we provide a comprehensive review of the fundamental reaction mechanism of electrochemical C–N coupling and strategies for improving the electrosynthesis of organonitrogen compounds. Additionally, we discuss the current challenges, extended electrochemical coupling reactions, and future roadmaps of electrochemical C–N coupling reactions. This review will strongly enhance the understanding of electrochemical C–N coupling reactions and propose a way forward for the electrosynthesis of organonitrogen compounds.
期刊介绍：
The development of the Current Opinion journals stemmed from the acknowledgment of the growing challenge for specialists to stay abreast of the expanding volume of information within their field. In Current Opinion in Electrochemistry, they help the reader by providing in a systematic manner:
1.The views of experts on current advances in electrochemistry in a clear and readable form.
2.Evaluations of the most interesting papers, annotated by experts, from the great wealth of original publications.
In the realm of electrochemistry, the subject is divided into 12 themed sections, with each section undergoing an annual review cycle:
• Bioelectrochemistry • Electrocatalysis • Electrochemical Materials and Engineering • Energy Storage: Batteries and Supercapacitors • Energy Transformation • Environmental Electrochemistry • Fundamental & Theoretical Electrochemistry • Innovative Methods in Electrochemistry • Organic & Molecular Electrochemistry • Physical & Nano-Electrochemistry • Sensors & Bio-sensors •
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