R. Alsaiari, Iman Shedaiwa, Fatima A. Al-Qadri, E. M. Musa, Huda Alqahtani, Faeza Alkorbi, Norah A. Alsaiari, Mervate M Mohamed
{"title":"Peganum Harmala L.植物作为绿色无毒吸附剂去除水中的铁元素","authors":"R. Alsaiari, Iman Shedaiwa, Fatima A. Al-Qadri, E. M. Musa, Huda Alqahtani, Faeza Alkorbi, Norah A. Alsaiari, Mervate M Mohamed","doi":"10.24425/aep.2024.149894","DOIUrl":null,"url":null,"abstract":"The present work focuses on examining the batch removal of Fe (III) from water using powdered Peganum Harmala seeds, characterized as FT-IR. In this work, several parameters are measured, including contact time, pH, Fe (III) concentration, reaction temperature effect, and adsorbent dose effect. Fe (III) adsorption was assessed using a UV-vis spectrophotometer at a wavelength of 620 nm. The findings demonstrated a positive correlation between the dosage of adsorbent and Fe (III) ions removal, with an increase in the adsorbent dose corresponding to higher elimination of Fe (III) ions. Therefore, the Langmuir isotherm model yielded more accurate equilibrium data compared to the Frendulich model. The kinetic data were mostly analyzed using a pseudo-second-order model rather than a pseudo-first-order model. Thermodynamic parameters, including enthalpy (ΔH◦), entropy (ΔS◦), and free energy (ΔG◦), were calculated. The adsorption process was found to be exothermic. Overall, Peganum Harmala was a favorable adsorbent for removing Fe (III) from aqueous solutions.","PeriodicalId":48950,"journal":{"name":"Archives of Environmental Protection","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Peganum Harmala L. plant as green non-toxic adsorbent for iron removal from water\",\"authors\":\"R. Alsaiari, Iman Shedaiwa, Fatima A. Al-Qadri, E. M. Musa, Huda Alqahtani, Faeza Alkorbi, Norah A. Alsaiari, Mervate M Mohamed\",\"doi\":\"10.24425/aep.2024.149894\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The present work focuses on examining the batch removal of Fe (III) from water using powdered Peganum Harmala seeds, characterized as FT-IR. In this work, several parameters are measured, including contact time, pH, Fe (III) concentration, reaction temperature effect, and adsorbent dose effect. Fe (III) adsorption was assessed using a UV-vis spectrophotometer at a wavelength of 620 nm. The findings demonstrated a positive correlation between the dosage of adsorbent and Fe (III) ions removal, with an increase in the adsorbent dose corresponding to higher elimination of Fe (III) ions. Therefore, the Langmuir isotherm model yielded more accurate equilibrium data compared to the Frendulich model. The kinetic data were mostly analyzed using a pseudo-second-order model rather than a pseudo-first-order model. Thermodynamic parameters, including enthalpy (ΔH◦), entropy (ΔS◦), and free energy (ΔG◦), were calculated. The adsorption process was found to be exothermic. Overall, Peganum Harmala was a favorable adsorbent for removing Fe (III) from aqueous solutions.\",\"PeriodicalId\":48950,\"journal\":{\"name\":\"Archives of Environmental Protection\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-03-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Archives of Environmental Protection\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.24425/aep.2024.149894\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Archives of Environmental Protection","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.24425/aep.2024.149894","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Peganum Harmala L. plant as green non-toxic adsorbent for iron removal from water
The present work focuses on examining the batch removal of Fe (III) from water using powdered Peganum Harmala seeds, characterized as FT-IR. In this work, several parameters are measured, including contact time, pH, Fe (III) concentration, reaction temperature effect, and adsorbent dose effect. Fe (III) adsorption was assessed using a UV-vis spectrophotometer at a wavelength of 620 nm. The findings demonstrated a positive correlation between the dosage of adsorbent and Fe (III) ions removal, with an increase in the adsorbent dose corresponding to higher elimination of Fe (III) ions. Therefore, the Langmuir isotherm model yielded more accurate equilibrium data compared to the Frendulich model. The kinetic data were mostly analyzed using a pseudo-second-order model rather than a pseudo-first-order model. Thermodynamic parameters, including enthalpy (ΔH◦), entropy (ΔS◦), and free energy (ΔG◦), were calculated. The adsorption process was found to be exothermic. Overall, Peganum Harmala was a favorable adsorbent for removing Fe (III) from aqueous solutions.
期刊介绍:
Archives of Environmental Protection is the oldest Polish scientific journal of international scope that publishes articles on engineering and environmental protection. The quarterly has been published by the Institute of Environmental Engineering, Polish Academy of Sciences since 1975. The journal has served as a forum for the exchange of views and ideas among scientists. It has become part of scientific life in Poland and abroad. The quarterly publishes the results of research and scientific inquiries by best specialists hereby becoming an important pillar of science. The journal facilitates better understanding of environmental risks to humans and ecosystems and it also shows the methods for their analysis as well as trends in the search of effective solutions to minimize these risks.