管材高强度低合金钢中焊接金属的微观结构与冲击韧性之间的关系(研究综述)

Yulia Karlina, Roman Kononenko, V. Ivancivsky, Maksim Popov, Fedor Derjugin, Vladislav Byankin
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引用次数: 0

摘要

导言。现代管道工业要求开发高强度和高韧性的材料,用于生产石油和天然气管道用钢。钢材生产和轧制技术的变化对焊材和连接技术提出了挑战。对于强度等级超过 830 兆帕的钢材来说,这一点更为关键,因为目前还没有专门的焊材审批法规。研究方法。不锈钢管道焊缝失效正成为管道行业的一个严重问题。在 HSLA 钢中,含有针状铁素体或针状铁素体为主相的多相微结构表现出良好的复合性能。本文重点介绍了利用现代扫描电子显微镜进行微结构分析、利用背散射电子(BSE)进行电子通道对比成像(ECCI)和基于电子背散射衍射(ORM)的取向显微镜,以及利用能量色散 X 射线光谱(XEDS)和二次电子(SE)观察表面形态进行成分分析的特征 X 射线所获得的结果。结果与讨论。本文分析了焊缝微观结构的特征及其与冲击韧性的关系。结果表明,由于涉及大量参数,根据钢焊接金属的微观结构特征预测冲击韧性非常复杂。这就要求钢材具有最佳的微观结构。令人满意的微观结构取决于多个因素,如化学成分、热加工工艺和加速冷却。合金元素对钢的性能有着复杂的影响,通常添加到钢成分中的合金添加剂包括 Mn、Mo、Ti、Nb 和 V。较长的冷却时间往往会提高高强度钢的韧性,降低焊缝熔敷的机械强度。焊接热循环会导致母材的机械性能发生显著变化。分析表明,冲击韧性在很大程度上取决于所研究材料多道焊缝的微观结构,其中包含多种异质性来源,如枝晶间偏析,有效晶粒尺寸也是造成局部冲击韧性值偏差较大的重要因素。在晶粒内夹杂物中成核的针状铁素体已被证明能产生细粒度的铁素体板交错排列,提供高抗拉强度和优异的韧性,因此是 C-Mn 钢焊接金属中理想的微观结构成分。与此同时,关于针状铁素体与韧性之间关系的讨论非常复杂,目前仍未结束。考虑到顶珠,将冲击韧性与针状铁素体联系起来并不是一个可靠的程序,即使对于单道熔敷焊接也是如此。冲击强度取决于多个因素,一般认为针状铁素体具有很强的作用,这是因为它具有细粒交错结构,可防止脆性裂纹通过劈裂扩展。针状铁素体的大角度边界和高位错密度提供了高强度和韧性。然而,对于相同数量的针状铁素体,根据钢中微合金元素含量的不同,可能会观察到不同的粘度值。对各种研究结果的分析表明,其他因素也会影响冲击强度。例如,沿 Charpy-V 缺口出现的微相对焊接金属的韧性至关重要。将 OM、SEM 和 EBSD 技术相结合,为不锈钢管道焊缝精细金属微观结构的金相学研究提供了一种有趣的方法。结论。本综述报告了有关管道钢焊缝微观结构因素的最具代表性的研究。其中包括对最重要的工艺变量、材料特性、规范准则以及接头的微观结构特征和机械特性的总结。本综述旨在使不同背景的读者受益,包括非焊接或材料科学家以及各种工业应用专家和研究人员。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Relationship between microstructure and impact toughness of weld metals in pipe high-strength low-alloy steels (research review)
Introduction. The modern pipeline industry requires the development of materials of high strength and toughness for the production of steels for oil and gas pipelines. Changes in steel production and rolling technologies have become a challenge for welding consumables and joining technologies. This is more critical for strength levels above 830 MPa, where there are no specific regulations for the approval of welding consumables. Research methods. The failure of stainless steel pipeline welds is becoming a serious problem in the pipeline industry. Multiphase microstructures containing acicular ferrite or an acicular ferrite-dominated phase exhibit good complex properties in HSLA steels. This paper focuses on the results obtained using modern methods of scanning electron microscopy for microstructural analysis, backscattered electrons (BSE) for electron channel contrast imaging (ECCI) and orientation microscopy based on electron backscatter diffraction (ORM), as well as characteristic X-rays for compositional analysis using energy-dispersive X-ray spectroscopy (XEDS) and secondary electrons (SE) for observing surface morphology. Results and discussion. This paper analyzes the characteristics of the microstructure of the weld and its relationship with impact toughness. It is shown that predicting impact toughness based on the microstructural characteristics of steel weld metals is complicated due to the large number of parameters involved. This requires an optimal microstructure of the steel. Satisfactory microstructure depends on several factors, such as chemical composition, hot work processing, and accelerated cooling. Alloying elements have a complex effect on the properties of steel, and alloying additives commonly added to the steel composition include Mn, Mo, Ti, Nb and V. From a metallurgical point of view, the choice of alloying elements and the metallurgical process can greatly influence the resulting microstructure. A longer cooling time tend to improve the toughness and reduce the mechanical strength of weld deposits on high-strength steels. Welding thermal cycles cause significant changes in the mechanical properties of the base material. The analysis showed that impact toughness strongly depends on the microstructure of the multi-pass weld of the material under study, which contains several sources of heterogeneity, such as interdendritic segregation, and the effective grain size can also be a significant factor explaining large deviations in local impact toughness values. Acicular ferrite nucleated in intragranular inclusions has been shown to produce a fine-grained interlocking arrangement of ferrite plates providing high tensile strength and excellent toughness, and is therefore a desirable microstructural constituent in C-Mn steel weld metals. At the same time, discussion regarding the relationship between acicular ferrite and toughness is very complex and still open at present. Relating impact toughness to acicular ferrite, taking into account the top bead, is not a reliable procedure, even for single-pass deposit welding. Impact strength depends on several factors, and the strong effect of acicular ferrite is generally recognized due to its fine-grained interlocking structure, which prevents the propagation of brittle cracks by cleavage. The large-angle boundaries and high dislocation density of acicular ferrite provide high strength and toughness. However, for the same amount of acicular ferrite, different viscosity values may be observed depending on the content of microalloying elements in the steel. An analysis of the results of various studies showed that other factors also affect the impact strength. For example, microphases present along the Charpy-V notch are critical for the toughness of weld metals. The combination of OM, SEM and EBSD techniques provides an interesting method for metallographic investigation of the refined metal microstructure of stainless steel pipeline welds. Conclusion. This review reports the most representative study regarding the microstructural factor in the weld of pipe steels. It includes a summary of the most important process variables, material properties, regulatory guidelines, and microstructure characteristics and mechanical properties of the joints. This review is intended to benefit readers from a variety of backgrounds, from non-welding or materials scientists to various industrial application specialists and researchers.
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