准噶尔盆地西哈拉雷特地区生物降解油的地球化学特征和来源相关性

IF 1.2 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS
Geofluids Pub Date : 2024-03-23 DOI:10.1155/2024/4832039
Zunjing Ma, Yingchun Zhang, Youjing Wang, Yancheng Liu
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引用次数: 0

摘要

长期以来,生物降解石油与其来源之间的关系一直是一个复杂而有争议的话题。哈拉雷特西部地区位于准噶尔盆地西北边缘的皮埃蒙特地区。当地和附近的马湖洼地都有丰城地层的源岩。为了确定该地区生物降解原油的来源,采用气相色谱-质谱法分析了生物降解原油的分子标记特征。结果表明,马湖凹陷附近二叠系凤城组源岩的玻璃光泽反射率(Ro)大于 1.3%,已进入凝析油和湿气的高成熟阶段;西哈拉雷特地区二叠系凤城组源岩处于成熟阶段,Ro 为 0.79%~1.13%。西哈拉来特地区石炭系地层中发现的原油样品中三环萜烯 C20-C21-C23 呈上升构型,与西哈拉来特地区及附近马湖凹陷中的凤城地层源岩特征一致。色谱光谱分析显示,原油经历了不同程度的生物降解。根据成熟度参数、盐度参数、新伽马烷指数和芳香烃参数等抗生物降解分子标记的应用,并结合碳氢化合物迁移路径分析,石炭纪石油来源于原生的凤城地层源岩。此外,还阐明了西哈拉雷特地区石油生物降解蚀变规律,增进了区域对生物降解石油与源岩关系的认识。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Geochemical Characteristic and Source Correlation of Biodegraded Oils from the Western Halaalate Area of Junggar Basin

The relationship between biodegraded oil and its source has long been a complex and contentious topic. The Western Halaalate area is located in the Piedmont area on the northwest margin of the Junggar Basin. Source rocks of the Fengcheng Formation exist both locally and in the nearby Mahu Depression. In order to determine the source of biodegraded crude oil in this area, the molecular marker characteristics of biodegraded crude oil were analyzed by gas chromatography-mass spectrometry. The results showed that the vitrinite reflectance (Ro) of source rocks of the Permian Fengcheng Formation in the nearby Mahu Depression is greater than 1.3% and has entered a high mature stage of condensate oil and moisture gas; the source rock of Permian Fengcheng Formation in Western Halaalate area is in a mature stage with Ro of 0.79%~1.13%. The ascending configuration of tricyclic terpenes C20-C21-C23 for the crude oil samples found in the Carboniferous strata of the Western Halaalate Area is consistent with the characteristics of the Fengcheng Formation source rocks, which are present in both the Western Halaalate Area and the nearby Mahu Depression. Chromatography spectrometry examination shows that crude oils have undergone a varying degree of biodegradation. The Carboniferous oil was originated from the in situ Fengcheng Formation source rocks based on the application of molecular markers resistant to biodegradation, such as maturity parameters, salinity parameters, the new gammacerane index, and aromatic hydrocarbon parameters, combined with the analysis of hydrocarbon migration pathway. In addition, the oil biodegradation alteration rules in the Western Halaalate area were clarified, which advances regional knowledge of the relationship between biodegraded oil and source rocks.

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来源期刊
Geofluids
Geofluids 地学-地球化学与地球物理
CiteScore
2.80
自引率
17.60%
发文量
835
期刊介绍: Geofluids is a peer-reviewed, Open Access journal that provides a forum for original research and reviews relating to the role of fluids in mineralogical, chemical, and structural evolution of the Earth’s crust. Its explicit aim is to disseminate ideas across the range of sub-disciplines in which Geofluids research is carried out. To this end, authors are encouraged to stress the transdisciplinary relevance and international ramifications of their research. Authors are also encouraged to make their work as accessible as possible to readers from other sub-disciplines. Geofluids emphasizes chemical, microbial, and physical aspects of subsurface fluids throughout the Earth’s crust. Geofluids spans studies of groundwater, terrestrial or submarine geothermal fluids, basinal brines, petroleum, metamorphic waters or magmatic fluids.
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