带有硫代氨基甲酸盐分子和萘发色团的钙[4]炔双功能受体的离子传感技术

IF 2.3 4区 化学 Q2 Agricultural and Biological Sciences
Horacio Gómez-Machuca, Cinthia Quiroga-Campano, Hernán Pessoa-Mahana, Claudio Saitz
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引用次数: 0

摘要

我们利用钙[4]炔开发了一种化学传感器,其特点是具有一个硫代氨基甲酸结合/传感单元和一个萘发色基团。我们的目标是利用紫外-可见光、氢核磁共振和红外光谱技术,了解这些化学传感器与各种阴离子和阳离子之间错综复杂的结合亲和力。我们的研究表明,这种化学传感器能与 Ag(I) 或 Cu(II) 形成复合物,并能通过硫代氨基脲的去质子化作用检测 CN- 或 F- 离子。为了了解这些相互作用的行为,我们的分析提供了受体与离子之间相互作用模式的信息。从观察到的红外光谱变化可以看出,硫代氨基甲酮取代基上的硫和亚胺氮是阳离子参与作用的重要部位。与阴离子相互作用的 HNMR 研究表明,硫代氨基甲酸氢的参与。在与阳离子形成络合物的过程中发生的相互作用会导致溶液或固体络合物的颜色发生变化,这很容易通过紫外-可见光谱进行追踪。我们的研究加深了人们对这种化学传感器的分子识别的理解,突出了它在离子选择性检测方面的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Ion sensing with a calix[4]arene bifunctional receptor with thiosemicarbazone moieties and naphthalene chromophore

Ion sensing with a calix[4]arene bifunctional receptor with thiosemicarbazone moieties and naphthalene chromophore

Ion sensing with a calix[4]arene bifunctional receptor with thiosemicarbazone moieties and naphthalene chromophore

We have developed a chemosensor using calix[4]arene, which features a thiosemicarbazone binding/sensing unit and a naphthalene chromogenic group. Our objective was to understand the intricate binding affinity of these chemosensors towards a diverse range of anions and cations using UV–Visible, HNMR and IR spectroscopic techniques. We showed that this chemosensor can form complexes with Ag(I) or Cu (II) and to detect CN or F ions by deprotonation of thiosemicarbazone. To understand the behavior of these interactions, our analysis provides information on the interaction patterns between the receptors and the ions. The sulfur and imine nitrogen on the thiosemicarbazone substituent are vital sites of engagement for cation ions, as evidenced by the observed changes in IR. HNMR studies for interaction with anions indicate the involvement of the thiosemicarbazone hydrogens. Interactions taking place during complex formation with cations lead to changes in the color of the solution or solid complex, easy to follow by UV–Vis spectrocopy. Our study improves the understanding of molecular recognition of this chemosensor, highlighting its potential for ion- selective detection.

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来源期刊
CiteScore
3.30
自引率
8.70%
发文量
0
审稿时长
3-8 weeks
期刊介绍: The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites. The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.
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