Petrography and stratigraphic Os isotopic ages of ferromanganese nodules from the Northwest Pacific east of Minamitorishima Island

The area offshore of Minamitorishima Island, Northwestern Pacific Ocean, contains large amounts of seafloor mineral resources such as ferromanganese (Fe–Mn) nodules, Fe–Mn crusts, and rare-earth element and yttrium (REY)-rich muds. In this study, we applied stratigraphic Os isotopic dating to a Fe–Mn nodule for the first time to date its formation/depositional age, and mineralogical and texturally characterized a complementary nodule. Based on macroscopic and microscopic observations, the studied Fe–Mn nodules can be divided into three layers: Layers L2, L1, and L0 from core to rim. Under the microscope, the Fe–Mn nodules are dominated by vernadite and Fe-oxyhydroxide. In particular, Layer L1 is dominated by banded-columnar vernadite and contains lower amounts of clay minerals derived from the detrital component than Layers L2 and L0. The bulk major and trace element geochemical compositions of sampled layers in the Fe–Mn nodules all plotted in the hydrogenous field in several discrimination diagrams. The Os isotopic ages determined by fitting to the paleo-seawater ¹⁸⁷Os/¹⁸⁸Os curve can be divided into three clusters (35.7–31.0, 19.0–9.0, and 4.0–1.0 Ma, corresponding to Layers L2, L1, and L0, respectively). These Os isotopic ages indicate that two periods of very slow growth or growth hiatuses occurred during the formation of the Fe–Mn nodule; these age gaps are related to the intermittent (discontinuous) timings of the beginning of Fe–Mn nodule formation offshore Minamitorishima Island.