通过简便的化学和物理合成实现过渡金属元素的相位控制。

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chemical record Pub Date : 2024-03-19 DOI:10.1002/tcr.202300378

Yuhan Liu, Ying Qin, Junyun Gao, Dr. Bo Huang

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引用次数: 0

摘要

金属的晶相是调整金属特性的重要因素，因此受到广泛关注。传统上，相控制是在有限的元素中通过苛刻的条件实现的，如通过高温实现面心立方铁的相控制。本综述总结了金属相控领域的大部分报告，包括铁、钴、镍、铜、钌、钯、铑、锇和金等元素。针对每种金属元素，系统地介绍了简便的相控方法，如外延生长、球磨、化学还原等。并深入讨论了这些方法的相应应用和相控机理。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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The Phase Control of Transition Metallic Elements via Facile Chemical and Physical Syntheses

The crystal phases of metals are important factors to tune the properties of metals, and therefore received extensive attention. Traditionally, phase control is performed within limited numbers of elements by harsh conditions, such as face-centered cubic Fe by high temperature. This review summarizes most reports in metal phase control area, including elements of Fe, Co, Ni, Cu, Ru, Pd, Rh, Os and Au. For every metallic element, the facile phase control methods are systematically introduced, such as epitaxial growth, ball milling, chemical reduction, etc. Their corresponding applications and the mechanisms for phase control are thoroughly discussed.

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来源期刊

Chemical record 化学-化学综合

CiteScore

11.00

自引率

3.00%

发文量

188

审稿时长

>12 weeks

期刊介绍： The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.