A. A. Shakirova, G. A. Gusev, E. V. Dementeva, A. A. Averin, T. B. Popova, M. V. Zamoryanskaya
{"title":"铽(Tb3+)在基于钇稳定立方二氧化锆的陶瓷中对铕(Eu3+)离子的敏化作用","authors":"A. A. Shakirova, G. A. Gusev, E. V. Dementeva, A. A. Averin, T. B. Popova, M. V. Zamoryanskaya","doi":"10.1134/s0030400x23030165","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>In this work, stabilized <i>f</i>-ZrO<sub>2</sub> ceramic samples with the compositions of (Zr<sub>0.82</sub>Y<sub>0.09</sub>Eu<sub>0.09</sub>)O<sub>1.91</sub>, (Zr<sub>0.82</sub>Y<sub>0.09</sub>Tb<sub>0.09</sub>)O<sub>1.91</sub> and (Zr<sub>0.82</sub>Y<sub>0.09</sub>Eu<sub>0.045</sub>Tb<sub>0.045</sub>)O<sub>1.91</sub> were studied. The elemental composition was studied by electron probe microanalysis, and the luminescent properties were studied by local cathodoluminescence (CL). An analysis of the Eu<sup>3+</sup> CL spectra confirmed the stabilization of the cubic phase in ceramics at room temperature. The study of the obtained CL spectra, the <sup>5</sup><i>D</i><sub>4</sub>–<sup>7</sup><i>F</i><sub>5</sub>Tb<sup>3+</sup> band luminescence decay kinetics, CL images and excitation spectra showed europium sensitization by terbium in (Zr<sub>0.82</sub>Y<sub>0.09</sub>Eu<sub>0.045</sub>Tb<sub>0.045</sub>)O<sub>1.91</sub>.</p>","PeriodicalId":723,"journal":{"name":"Optics and Spectroscopy","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2024-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sensitization of Europium (Eu3+) Ions by Terbium (Tb3+) in Ceramics Based on Yttrium Stabilized Cubic Zirconium Dioxide\",\"authors\":\"A. A. Shakirova, G. A. Gusev, E. V. Dementeva, A. A. Averin, T. B. Popova, M. V. Zamoryanskaya\",\"doi\":\"10.1134/s0030400x23030165\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>In this work, stabilized <i>f</i>-ZrO<sub>2</sub> ceramic samples with the compositions of (Zr<sub>0.82</sub>Y<sub>0.09</sub>Eu<sub>0.09</sub>)O<sub>1.91</sub>, (Zr<sub>0.82</sub>Y<sub>0.09</sub>Tb<sub>0.09</sub>)O<sub>1.91</sub> and (Zr<sub>0.82</sub>Y<sub>0.09</sub>Eu<sub>0.045</sub>Tb<sub>0.045</sub>)O<sub>1.91</sub> were studied. The elemental composition was studied by electron probe microanalysis, and the luminescent properties were studied by local cathodoluminescence (CL). An analysis of the Eu<sup>3+</sup> CL spectra confirmed the stabilization of the cubic phase in ceramics at room temperature. The study of the obtained CL spectra, the <sup>5</sup><i>D</i><sub>4</sub>–<sup>7</sup><i>F</i><sub>5</sub>Tb<sup>3+</sup> band luminescence decay kinetics, CL images and excitation spectra showed europium sensitization by terbium in (Zr<sub>0.82</sub>Y<sub>0.09</sub>Eu<sub>0.045</sub>Tb<sub>0.045</sub>)O<sub>1.91</sub>.</p>\",\"PeriodicalId\":723,\"journal\":{\"name\":\"Optics and Spectroscopy\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-03-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Optics and Spectroscopy\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1134/s0030400x23030165\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"OPTICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optics and Spectroscopy","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1134/s0030400x23030165","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"OPTICS","Score":null,"Total":0}
Sensitization of Europium (Eu3+) Ions by Terbium (Tb3+) in Ceramics Based on Yttrium Stabilized Cubic Zirconium Dioxide
Abstract
In this work, stabilized f-ZrO2 ceramic samples with the compositions of (Zr0.82Y0.09Eu0.09)O1.91, (Zr0.82Y0.09Tb0.09)O1.91 and (Zr0.82Y0.09Eu0.045Tb0.045)O1.91 were studied. The elemental composition was studied by electron probe microanalysis, and the luminescent properties were studied by local cathodoluminescence (CL). An analysis of the Eu3+ CL spectra confirmed the stabilization of the cubic phase in ceramics at room temperature. The study of the obtained CL spectra, the 5D4–7F5Tb3+ band luminescence decay kinetics, CL images and excitation spectra showed europium sensitization by terbium in (Zr0.82Y0.09Eu0.045Tb0.045)O1.91.
期刊介绍:
Optics and Spectroscopy (Optika i spektroskopiya), founded in 1956, presents original and review papers in various fields of modern optics and spectroscopy in the entire wavelength range from radio waves to X-rays. Topics covered include problems of theoretical and experimental spectroscopy of atoms, molecules, and condensed state, lasers and the interaction of laser radiation with matter, physical and geometrical optics, holography, and physical principles of optical instrument making.